Title : ( A facile access to highly functionalized triphenylphosphoranylidene succinimides through a three-component reaction and DFT investigation on the reaction mechanism )
Authors: Abbas Ali Esmaeili , Hanieh Khoddam-Mohammadi , Abbas Moradi , Ehsan Davamdar , Mohammad Izadyar , Mohammad Khavani , Mohammad Reza Islami ,
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Abstract
Novel, one-pot, three-component reaction of the zwitterions generated in situ from triphenylphosphine and acetylenic esters with aroyl isocynate is described. The reaction afforded N-benzoyl-2-triphenylphosphoranylidene succinimide derivatives in good to high yields without using any catalyst or activation. Structural, electronic, energetic and mechanistic details of the reaction are also revealed by density functional theory (DFT) calculations, which strongly support the exclusive formation of the products.
Keywords
, Benzoylisocyanates, Triphenyphosphine, N-Benzoylsuccinimides, Succinimides, Dialkyl acetylenedicarboxylate, Mechanism, DFT
@article{paperid:1042791,
author = {Esmaeili, Abbas Ali and Hanieh Khoddam-Mohammadi and Abbas Moradi and Ehsan Davamdar and Izadyar, Mohammad and Khavani, Mohammad and Mohammad Reza Islami},
title = {A facile access to highly functionalized triphenylphosphoranylidene succinimides through a three-component reaction and DFT investigation on the reaction mechanism},
journal = {RSC Advances},
year = {2014},
volume = {4},
number = {4},
month = {August},
issn = {2046-2069},
pages = {37900--37907},
numpages = {7},
keywords = {Benzoylisocyanates; Triphenyphosphine; N-Benzoylsuccinimides; Succinimides; Dialkyl acetylenedicarboxylate; Mechanism; DFT},
}
%0 Journal Article
%T A facile access to highly functionalized triphenylphosphoranylidene succinimides through a three-component reaction and DFT investigation on the reaction mechanism
%A Esmaeili, Abbas Ali
%A Hanieh Khoddam-Mohammadi
%A Abbas Moradi
%A Ehsan Davamdar
%A Izadyar, Mohammad
%A Khavani, Mohammad
%A Mohammad Reza Islami
%J RSC Advances
%@ 2046-2069
%D 2014
