Organic Chemistry Research, Volume (3), No (1), Year (2017-3) , Pages (50-60)

Title : ( Basic Task-specific Ionic Liquid as Catalyst and Reaction Medium: A Green Protocol for the Synthesis of 4-Oxo-6-aryl-2-thioxo-1,2,3,4- tetrahydropyrimidine-5-carbonitrile Derivatives )

Authors: Maede Hasanpour Mansour , Hossein Eshghi , mehdi mirzaei ,

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Abstract

A novel basic ionic liquid, based on imidazolium cation, is designed, synthesized and successfully used as a catalyst for the one-pot synthesis of 4-oxo-6-aryl-2-thioxo-1,2,3,4-tetrahydropyrimidine-5-carbonitrile derivatives. The remarkable features of this new catalyst are its ethyleneoxy bridge which participates in dissolving organic compound in the ionic liquid and its strong base counterion. The application of this ionic liquid is studied in a new one-pot method for the synthesis of heterocyclic compounds under solvent-free conditions. A simple and convenient procedure, high conversion, reusability of catalyst, easy purification and shorter reaction time are the advantageous features of this method.

Keywords

, Ionic liquid, Imidazolium cation, Pyrimidine, Reusable catalyst, Ethyleneoxy bridge
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@article{paperid:1063935,
author = {Hasanpour Mansour, Maede and Eshghi, Hossein and Mirzaei, Mehdi},
title = {Basic Task-specific Ionic Liquid as Catalyst and Reaction Medium: A Green Protocol for the Synthesis of 4-Oxo-6-aryl-2-thioxo-1,2,3,4- tetrahydropyrimidine-5-carbonitrile Derivatives},
journal = {Organic Chemistry Research},
year = {2017},
volume = {3},
number = {1},
month = {March},
issn = {2383-242X},
pages = {50--60},
numpages = {10},
keywords = {Ionic liquid; Imidazolium cation; Pyrimidine; Reusable catalyst; Ethyleneoxy bridge},
}

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%0 Journal Article
%T Basic Task-specific Ionic Liquid as Catalyst and Reaction Medium: A Green Protocol for the Synthesis of 4-Oxo-6-aryl-2-thioxo-1,2,3,4- tetrahydropyrimidine-5-carbonitrile Derivatives
%A Hasanpour Mansour, Maede
%A Eshghi, Hossein
%A Mirzaei, Mehdi
%J Organic Chemistry Research
%@ 2383-242X
%D 2017

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