Title : ( Effects of Compatibilizer and Thermoplastic Starch (TPS) Concentration on Morphological, Rheological, Tensile, Thermal and Moisture Sorption Properties of Plasticized Polylactic Acid/TPS Blends )
Authors: mohammadreza abdollahi moghaddam , Seyed Mohammad Ali Razavi , Yousef Jahani ,
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Abstract
The blends of polylactic acid plasticized with acetyl tributyl citrate (P-PLA) and thermoplastic wheat starch (TPS) were prepared by a co-rotating twin screw extruder and the effect of maleic anhydride grafted PLA (PLA-g-MA) content as reactive compatibilizer on blends compatibility through morphological, rheological and tensile properties of the blends was investigated. Considerable improvement in properties of P-PLA/TPS (70/30 w/w) blend with incorporating the optimum PLA-g-MA content of 4 phr was achieved as this blend exhibited better morphological and rheological properties with an increase by 158 and 276% in tensile strength and elongation at break, respectively, compared to the uncompatibilized blend. Also the thermal stability and moisture sorption properties of the blends as effected by TPS content were studied. Decreasing in thermal stability and increasing in equilibrium moisture content of the blends were observed with progressively increasing of TPS content. For prediction the moisture sorption behaviour of blends with various TPS contents at different relative humidity, the moisture sorption isotherm data were modeled by GAB (Guggenheim–Anderson–de Boer) model.
Keywords
, Compatibilization, Packaging, Polylactic acid, Thermoplastic starch
@article{paperid:1067419,
author = {Abdollahi Moghaddam, Mohammadreza and Razavi, Seyed Mohammad Ali and Yousef Jahani},
title = {Effects of Compatibilizer and Thermoplastic Starch (TPS) Concentration on Morphological, Rheological, Tensile, Thermal and Moisture Sorption Properties of Plasticized Polylactic Acid/TPS Blends},
journal = {Journal of Polymers and the Environment},
year = {2018},
volume = {26},
number = {8},
month = {February},
issn = {1566-2543},
pages = {3202--3215},
numpages = {13},
keywords = {Compatibilization; Packaging; Polylactic acid; Thermoplastic starch},
}
%0 Journal Article
%T Effects of Compatibilizer and Thermoplastic Starch (TPS) Concentration on Morphological, Rheological, Tensile, Thermal and Moisture Sorption Properties of Plasticized Polylactic Acid/TPS Blends
%A Abdollahi Moghaddam, Mohammadreza
%A Razavi, Seyed Mohammad Ali
%A Yousef Jahani
%J Journal of Polymers and the Environment
%@ 1566-2543
%D 2018
