Title : ( 2,2Bipyridine)(pyridine-2,6-dicarboxylato)oxidovanadium(IV) ethanol monosolvate )
Authors: Hossein Aghabozorg , Elnaz Tavakoli , Masoud Mirzaei Shahrabi ,
Full TextAbstract
In the title compound, [V(C7H3NO4)O(C10H8N2)]C2H5OH, the VIV atom exhibits a distorted octahedral coordination environment formed by two pyridyl N atoms of 2,20-bipyridine (bpy), the vanadyl O atom, and two carboxylate O atoms and one pyridyl N atom of the tridentate pyridine-2,6-dicarboxylate (pydc2) ligand. The pyridyl N atom of the pydc2 anion and one pyridyl N atom of bpy occupy the axial positions. O— H O hydrogen bonds involving the ethanol solvent molecule as donor and a carboxylate O atom as acceptor atoms, as well as C—H O hydrogen bonds, together with – stacking interactions between adjacent aromatic rings (average centroid–centroid distance = 3.577 A ° ), seem to be effective in the stabilization of the crystal packing, resulting in the formation of a three-dimensional structure.
Keywords
, single, crystal X, ray study; T = 296 K; mean (C–C) = 0.008 A° ; R factor = 0.058; wR factor = 0.144; data, to, parameter ratio = 11.3.
@article{paperid:1019984,
author = {Hossein Aghabozorg and Elnaz Tavakoli and Mirzaei Shahrabi, Masoud},
title = {2,2Bipyridine)(pyridine-2,6-dicarboxylato)oxidovanadium(IV) ethanol monosolvate},
journal = {Acta Crystallographica Section E: Structure Reports Online},
year = {2011},
volume = {67},
number = {67},
month = {January},
issn = {1600-5368},
pages = {248--249},
numpages = {1},
keywords = {single-crystal X-ray study; T = 296 K; mean (C–C) = 0.008 A°
;
R factor = 0.058; wR factor = 0.144; data-to-parameter ratio = 11.3.},
}
%0 Journal Article
%T 2,2Bipyridine)(pyridine-2,6-dicarboxylato)oxidovanadium(IV) ethanol monosolvate
%A Hossein Aghabozorg
%A Elnaz Tavakoli
%A Mirzaei Shahrabi, Masoud
%J Acta Crystallographica Section E: Structure Reports Online
%@ 1600-5368
%D 2011
