This study investigated the antioxidant potential of Bene hull methanolic extract (BHME) in mitigating lipid oxidation in vegetable oils across four systems (oil-in-water emulsions and bulk oils, both with and without Fe+2). The BHME s free radical-scavenging assay and ferric reducing abilities were compared with natural (α-tocopherol, CEX) and synthetic (BHT) antioxidants. The research analyzed different BHME concentrations (0, 400, 800, and 1600 ppm) and evaluated the effects of storage time on lipid oxidation, monitored through Peroxide Value (PV) and Carbonyl Value (CV) measurements. An array of statistical analyses, including ANOVA and a robust Support Vector Machine (SVM) model were employed to predict oxidation dynamics. The findings revealed that BHME demonstrated significant antioxidant activity, comparable to BHT, with both showing similar IC50 values (7.59 μg/ml and 7.45 μg/ml, respectively. In emulsions, PV increased 2.5 times at 800 ppm and 13 times at 1600 ppm compared to bulk oils. The presence of Fe+2 led to a 40 % higher PV in emulsions. CV values rose by 35 and 56 units at 800 and 1600 ppm, respectively, and increased six fold over the storage period. The SVM model showed high predictive accuracy, with R2 values exceeding 0.97. Response surface graphs indicated that storage time had a more pronounced effect on PV and CV than antioxidant concentration. This study highlights BHME\\\\\\\'s potential as an effective natural antioxidant, particularly in bulk oils, and demonstrates the utility of SVM for analyzing lipid oxidation. These findings provide valuable insights for improving the oxidative stability and shelf life of lipid-based food products.

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