Title : ( Conversion of Alcohols, Thiols, and Trimethysilyl Ethers to AlkyCyanides Using Triphenylphosphine )
Authors: Batool Akhlaghinia ,
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Abstract
Triphenylphosphine and 2,3-dichloro-5,6-dicyanobenzoquinone afford an adduct, which in the presence of n-Bu4NCN converts alcohols, thiols, and trimethylsilyl ethers into their corresponding alkyl cyanides in good to excellent yields at room temperature. This method is highly selective for the conversion of 1° alcohols in the presence of 2° and 3° ones, thiols and silyl ethers.
Keywords
, Triphenylphosphine , 2, 3-dichloro-5, 6-dicyanobenzoquinone
@article{paperid:1008630,
author = {Akhlaghinia, Batool},
title = {Conversion of Alcohols, Thiols, and Trimethysilyl Ethers to AlkyCyanides Using Triphenylphosphine},
journal = {Journal of Organic Chemistry},
year = {2004},
month = {February},
issn = {0022-3263},
keywords = {Triphenylphosphine ;2;3-dichloro-5;6-dicyanobenzoquinone},
}
%0 Journal Article
%T Conversion of Alcohols, Thiols, and Trimethysilyl Ethers to AlkyCyanides Using Triphenylphosphine
%A Akhlaghinia, Batool
%J Journal of Organic Chemistry
%@ 0022-3263
%D 2004
