Title : ( A New and Convenient Method of Generating Alkyl Isocyanates fromAlcohols, Thiols and Trimethylsilyl Ethers Using Triphenylphosphine/2,3-Dichloro-5,6-dicyanobenzoquinone/Bu4NOCN )
Authors: Batool Akhlaghinia ,
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Abstract
Alkyl isocyanates are prepared in good to excellent yields by treatment of alcohols, thiols and trimethylsilyl ethers with triphenylphosphine/2,3-dichloro-5,6-dicyanobenzoquinone/ Bu4NOCN in acetonitrile. This method is highly selective for conversion of primary alcohols to alkyl isocyanates in the presence of secondary and tertiary alcohols, thiols and trimethysilyl ethers.
Keywords
, triphenylphosphine, 2, 3-dichloro-5, 6-dicyanobenzoquinone, alcohol, thiol, trimethylsilyl ether, alkyl isocyanate
@article{paperid:1008807,
author = {Akhlaghinia, Batool},
title = {A New and Convenient Method of Generating Alkyl Isocyanates fromAlcohols, Thiols and Trimethylsilyl Ethers Using Triphenylphosphine/2,3-Dichloro-5,6-dicyanobenzoquinone/Bu4NOCN},
journal = {Synthesis},
year = {2005},
month = {June},
issn = {0039-7881},
keywords = {triphenylphosphine; 2;3-dichloro-5;6-dicyanobenzoquinone;
alcohol; thiol; trimethylsilyl ether; alkyl isocyanate},
}
%0 Journal Article
%T A New and Convenient Method of Generating Alkyl Isocyanates fromAlcohols, Thiols and Trimethylsilyl Ethers Using Triphenylphosphine/2,3-Dichloro-5,6-dicyanobenzoquinone/Bu4NOCN
%A Akhlaghinia, Batool
%J Synthesis
%@ 0039-7881
%D 2005
