Title : ( Novel and Highly Selective Conversion of Alcohols and Thiols to Alkyl Nitriteswith Triphenylphosphine/2,3-Dichloro-5,6-dicyanobenzoquinone/Bu4NNO2System )
Authors: Hossein Behniafar , Batool Akhlaghinia , Ali Reza Pourali , Sedigheh Habibian ,
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Abstract
Alkyl nitrites were prepared in good to excellent yields by treatment of alcohols and thiols with triphenylphosphine/2,3- dichloro-5,6-dicyanobenzoquinone/Bu4NNO2 in acetonitrile. This method is highly selective for the conversion of primary alcohols to alkyl nitrites in the presence of secondary and tertiary alcohols and thiols.
Keywords
, triphenylphosphine, 2, 3-dichloro-5, 6-dicyanobenzoquinone, alkyl nitrite, alcohol, thiol
@article{paperid:1009067,
author = {Hossein Behniafar and Akhlaghinia, Batool and Ali Reza Pourali and Sedigheh Habibian},
title = {Novel and Highly Selective Conversion of Alcohols and Thiols to Alkyl Nitriteswith Triphenylphosphine/2,3-Dichloro-5,6-dicyanobenzoquinone/Bu4NNO2System},
journal = {Synthesis},
year = {2004},
month = {April},
issn = {0039-7881},
keywords = {triphenylphosphine; 2;3-dichloro-5;6-dicyanobenzoquinone;
alkyl nitrite; alcohol; thiol},
}
%0 Journal Article
%T Novel and Highly Selective Conversion of Alcohols and Thiols to Alkyl Nitriteswith Triphenylphosphine/2,3-Dichloro-5,6-dicyanobenzoquinone/Bu4NNO2System
%A Hossein Behniafar
%A Akhlaghinia, Batool
%A Ali Reza Pourali
%A Sedigheh Habibian
%J Synthesis
%@ 0039-7881
%D 2004
