Title : ( N-Benzyl-2-propanaminium O-methyl trichloroacetamidophosphate )
Authors: Mehrdad Pourayoubi , Fahimeh Sabbaghi ,
Full TextAbstract
The title compound, C13H20Cl3N2O4P, was prepared by the reaction of N-isopropylbenzylamine and CCl3C(O)N(H)- P(O)Cl2, followed by crystallization from CH3OH and CH3CN. Centrosymmetric dimers of anions are hydrogenbonded to neighbouring cations (via –P—O H—N– and –C O H—N– hydrogen bonds) in a one-dimensional polymeric chain. Furthermore, a Cl Cl interaction (3.242 A ˚ ) and a C—H short contact are present in the crystal structure, the former between two adjacent anions and the latter between two neighbouring cations.
Keywords
, single, crystal X, ray study; T = 120 K; mean (C–C) = 0.003 A° ; R factor = 0.032; wR factor = 0.076; data, to, parameter ratio = 18.0.
@article{paperid:1011642,
author = {Pourayoubi, Mehrdad and Fahimeh Sabbaghi},
title = {N-Benzyl-2-propanaminium O-methyl trichloroacetamidophosphate},
journal = {Acta Crystallographica Section E: Structure Reports Online},
year = {2007},
volume = {63},
number = {11},
month = {November},
issn = {1600-5368},
keywords = {single-crystal X-ray study; T = 120 K; mean (C–C) = 0.003 A°
;
R factor = 0.032; wR factor = 0.076; data-to-parameter ratio = 18.0.},
}
%0 Journal Article
%T N-Benzyl-2-propanaminium O-methyl trichloroacetamidophosphate
%A Pourayoubi, Mehrdad
%A Fahimeh Sabbaghi
%J Acta Crystallographica Section E: Structure Reports Online
%@ 1600-5368
%D 2007
