Title : ( Pentakis(L-prolinium) dodecatungstoborate trihydrate )
Authors: Akbar Raissi Shabari , Mehrdad Pourayoubi , Dena Ghamari ,Abstract
The title polyoxometalate-based organic-inorganic hybrid compound, (C5H10NO2)5[BW12O40]3H2O, consists of one - Keggin-type [BW12O40]5 polyoxoanion, five crystallographically independent l-prolinium cations and three uncoordinated water molecules. The polyoxoanion shows characteristic features with respect to bond lengths and angles. Several N— H O and O—H O hydrogen bonds between the organic cations, inorganic anions and crystal water molecules lead to a three-dimensional supramolecular structure.
Keywords
, single, crystal X, ray study; T = 100 K; mean (C–C) = 0.017 A°; Hatom completeness 90%; R factor = 0.035; wR factor = 0.088; data, to, parameter ratio = 19.0.@article{paperid:1012604,
author = {Akbar Raissi Shabari and Pourayoubi, Mehrdad and Dena Ghamari},
title = {Pentakis(L-prolinium) dodecatungstoborate trihydrate},
journal = {Acta Crystallographica Section E: Structure Reports Online},
year = {2009},
volume = {65},
number = {12},
month = {December},
issn = {1600-5368},
pages = {1586--1586},
numpages = {0},
keywords = {single-crystal X-ray study; T = 100 K; mean (C–C) = 0.017 A°; Hatom
completeness 90%; R factor = 0.035; wR factor = 0.088; data-to-parameter
ratio = 19.0.},
}
%0 Journal Article
%T Pentakis(L-prolinium) dodecatungstoborate trihydrate
%A Akbar Raissi Shabari
%A Pourayoubi, Mehrdad
%A Dena Ghamari
%J Acta Crystallographica Section E: Structure Reports Online
%@ 1600-5368
%D 2009