Title : ( An ionic 2D inorganic–organic hybrid of tris[((1H-tetrazol-5-yl)methyl) morpholine] dodecatungstophosphate(V) pentahydrate: Synthesis X-ray crystal structure and spectroscopic characterizations )
Authors: M. Nikpour , Mohsen Nikpour , Hossein Eshtiagh Hosseini , Masoud Mirzaei Shahrabi , Masoud Mirzaei Shahrabi , A. Aghaie Kaju , Amir Aghaei Kaju , Ya Guang Chen , S. Zarinabadi , Soroush Zarinabadi ,
Full TextAbstract
Abstract A unique ionic hybrid material [C6H12N5O]3[(PO4)W12O36] 5H2O has been synthesized from the reaction of ((1H-tetrazole-5- yl)methyl)morpholine and a-H3[(PO4)W12O36] 21H2O. It has successfully been characterized by elemental analysis, IR and 1H NMR spectroscopies, TGA and single-crystal X-ray diffraction method. The title compound is onstructed from the three [C6H12N5O]+ cations and a-Keggin [(PO4)W12O36]3 polyoxoanion. The most remarkable structural feature of this hybrid can be described as two-dimensional inorganic infinite plane-like (2D/1[(PO4)W12O36]3 ) which forming via van derWaals interactions along the x axis.
Keywords
Polyoxometalate; Inorganic–organic hybrid; Morpholine; Dodecatungstophosphate; Crystal structure
@article{paperid:1014050,
author = {M. Nikpour and Mohsen Nikpour and Eshtiagh Hosseini, Hossein and Mirzaei Shahrabi, Masoud and Mirzaei Shahrabi, Masoud and A. Aghaie Kaju and Amir Aghaei Kaju and Ya Guang Chen and S. Zarinabadi and Soroush Zarinabadi},
title = {An ionic 2D inorganic–organic hybrid of tris[((1H-tetrazol-5-yl)methyl) morpholine] dodecatungstophosphate(V) pentahydrate: Synthesis X-ray crystal structure and spectroscopic characterizations},
journal = {Chinese Chemical Letters},
year = {2010},
volume = {21},
number = {21},
month = {January},
issn = {1001-8417},
pages = {501--505},
numpages = {4},
keywords = {Polyoxometalate; Inorganic–organic hybrid; Morpholine; Dodecatungstophosphate; Crystal structure},
}
%0 Journal Article
%T An ionic 2D inorganic–organic hybrid of tris[((1H-tetrazol-5-yl)methyl) morpholine] dodecatungstophosphate(V) pentahydrate: Synthesis X-ray crystal structure and spectroscopic characterizations
%A M. Nikpour
%A Mohsen Nikpour
%A Eshtiagh Hosseini, Hossein
%A Mirzaei Shahrabi, Masoud
%A Mirzaei Shahrabi, Masoud
%A A. Aghaie Kaju
%A Amir Aghaei Kaju
%A Ya Guang Chen
%A S. Zarinabadi
%A Soroush Zarinabadi
%J Chinese Chemical Letters
%@ 1001-8417
%D 2010
