Title : ( NiO/MgO/SiO2 supported cobalt(II) tetrasulfophthalocyanine as an efficient, selective, and recyclable catalyst for the aerobic oxidation of thiols to disulfides )
Authors: Hossein Eshtiagh Hosseini , Mohammad Reza Housaindokht , samad shoghpour bayraq ,
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Abstract
Abstract An efficient and convenient method is reported for the selective aerobic oxidation of thiols to the corresponding disulfides using NiO/MgO/SiO2 (15 wt% NiO, Si/Mg = 3) supported cobalt(II) tetrasulfophthalocyanine as the catalyst in ethyl acetate at room temperature. The method is applicable to aromatic, aliphatic, and heterocyclic thiols. The catalyst can be recycled and reused for several times without any significant loss of its catalytic activity.
Keywords
Oxidation Thiols Disulfides Cobalt(II) tetrasulfophthalocyanine
@article{paperid:1016670,
author = {Eshtiagh Hosseini, Hossein and Housaindokht, Mohammad Reza and Shoghpour Bayraq, Samad},
title = {NiO/MgO/SiO2 supported cobalt(II) tetrasulfophthalocyanine as an efficient, selective, and recyclable catalyst for the aerobic oxidation of thiols to disulfides},
journal = {Reaction Kinetics, Mechanisms and Catalysis},
year = {2010},
volume = {100},
month = {July},
issn = {1878-5190},
pages = {105--110},
numpages = {5},
keywords = {Oxidation Thiols Disulfides Cobalt(II) tetrasulfophthalocyanine},
}
%0 Journal Article
%T NiO/MgO/SiO2 supported cobalt(II) tetrasulfophthalocyanine as an efficient, selective, and recyclable catalyst for the aerobic oxidation of thiols to disulfides
%A Eshtiagh Hosseini, Hossein
%A Housaindokht, Mohammad Reza
%A Shoghpour Bayraq, Samad
%J Reaction Kinetics, Mechanisms and Catalysis
%@ 1878-5190
%D 2010
