Title : ( Bis(2-amino-4-methylpyridinium)trans-diaquabis(pyrazine-2,3-dicarboxylato)cuprate(II) hexahydrate )
Authors: Hossein Eshtiagh Hosseini , Fabienne Gschwind , Nafiseh Alfi , Masoud Mirzaei Shahrabi , Masoud Mirzaei Shahrabi ,
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Abstract
The title compound, (C6H9N2)2[Cu(C6H2N2O4)2(H2O)2]- 6H2O, consists of a mononuclear trans-[Cu(pzdc)2(H2O)2]2 dianion (pzdc is pyrazine-2,3-dicarboxylate) and two [ampyH]+ cations (ampy is 2-amino-4-methylpyridine) with six water molecules of solvation. The CuII atom is hexacoordinated by two pzdc groups and two water molecules. The coordinated water molecules are in trans-diaxial positions and the pzdc dianion acts as a bidentate ligand through an O atom of the carboxylate group and the N atom of the pyrazine ring. There are diverse hydrogen-bonding interactions, such as N— H O and O—H O contacts, which lead to the formation of a three-dimensional supramolecular architecture.
Keywords
, single, crystal X, ray study; T = 293 K; mean (C–C) = 0.002 A° ; R factor = 0.036; wR factor = 0.092; data, to, parameter ratio = 17.5.
@article{paperid:1017431,
author = {Eshtiagh Hosseini, Hossein and Fabienne Gschwind and Alfi, Nafiseh and Mirzaei Shahrabi, Masoud and Mirzaei Shahrabi, Masoud},
title = {Bis(2-amino-4-methylpyridinium)trans-diaquabis(pyrazine-2,3-dicarboxylato)cuprate(II) hexahydrate},
journal = {Acta Crystallographica Section E: Structure Reports Online},
year = {2010},
volume = {66},
number = {7},
month = {May},
issn = {1600-5368},
keywords = {single-crystal X-ray study; T = 293 K; mean (C–C) = 0.002 A°
;
R factor = 0.036; wR factor = 0.092; data-to-parameter ratio = 17.5.},
}
%0 Journal Article
%T Bis(2-amino-4-methylpyridinium)trans-diaquabis(pyrazine-2,3-dicarboxylato)cuprate(II) hexahydrate
%A Eshtiagh Hosseini, Hossein
%A Fabienne Gschwind
%A Alfi, Nafiseh
%A Mirzaei Shahrabi, Masoud
%A Mirzaei Shahrabi, Masoud
%J Acta Crystallographica Section E: Structure Reports Online
%@ 1600-5368
%D 2010
