Title : ( Synthesis and Spectroscopic Characterization of Two New Phosphorylamidates, Crystal Structure of [(C6H4(3-CH3)NH)]9[P(O)]3(C2H5O)3 )
Authors: monireh negari , Mehrdad Pourayoubi , Hossein Eshtiagh Hosseini ,
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Abstract
Phosphoramidates are an important class of compounds due to their different applications in medicine, pharmacology, agriculture and coordination chemistry. Some new phosphorus compounds with formula [(C6H4(3-CH3)NH)]9[P(O)]3(C2H5O)3 (1), [(C6H5O)2P(O)(NHC6H11)] (2), has been synthesized and characterized by 1H, 13C and 31P{1H} NMR, IR. Moreover single crystal X-ray diffraction was performed for compound 1. Single crystal X-ray analysis shows that it belongs to triclinic system, space group P-1, with a = 12.5401(11) Å, b = 12.8961(7) Å, c = 23.8258(10) Å, = 92.411(4), = 101.934(5), = 114.075(6), Z = 6. The crystal lattice of compound 1 contains three crystallographically independent phosphoramidate molecules as well as three hydrogenbonded C2H5OH molecules with slightly differences in the bond lengths, angles and torsion angles. The O-H…O and N-H…O hydrogen bonds are responsible for the extended chain aggregation in crystal network.
Keywords
, Phosphoramidate, crystal structure, X-Ray Crytallography.
@inproceedings{paperid:1017672,
author = {Negari, Monireh and Pourayoubi, Mehrdad and Eshtiagh Hosseini, Hossein},
title = {Synthesis and Spectroscopic Characterization of Two New Phosphorylamidates, Crystal Structure of [(C6H4(3-CH3)NH)]9[P(O)]3(C2H5O)3},
booktitle = {12th Iranian Inorganic Chemistry Conference},
year = {2010},
location = {Rasht, IRAN},
keywords = {Phosphoramidate; crystal structure; X-Ray Crytallography.},
}
%0 Conference Proceedings
%T Synthesis and Spectroscopic Characterization of Two New Phosphorylamidates, Crystal Structure of [(C6H4(3-CH3)NH)]9[P(O)]3(C2H5O)3
%A Negari, Monireh
%A Pourayoubi, Mehrdad
%A Eshtiagh Hosseini, Hossein
%J 12th Iranian Inorganic Chemistry Conference
%D 2010
