Acta Crystallographica Section E: Structure Reports Online, ( ISI ), Volume (66), No (66), Year (2010-9) , Pages (1318-1319)

Title : ( Bis(9-aminoacridinium) bis(pyridine-2,6-dicarboxylato)cuprate(II) trihydrate )

Authors: Hossein Aghabozorg , Shabnam Ahmadvand , Masoud Mirzaei Shahrabi , Hamid Reza Khavasi ,

Citation: BibTeX | EndNote

Abstract

The asymmetric unit of the title compound, (C13H11N2)2- [Cu(C7H3NO4)2]3H2O or (9-aminoAcr)[Cu(pydc)2]3H2O, contains a Cu(pydc)2 (pydc = pyridine-2,6-dicarboxylate) anion, two protonated 9-aminoacridine (9-aminoAcr)+ counter-ions and three uncoordinated water molecules. The anion contains a six-coordinated Cu(II) atom within a distorted octahedral geometry. Non-covalent interactions i.e. N—H  O and O—H  O hydrogen bonds and intermolecular – contacts between the pyridine rings [centroid–centroid distance = 3.7773 (13) A ˚ ] and acridine rings [centroid–centroid distance = 3.4897 (13), 3.7784 (14) and 3.8627 (15) A ˚ ] result in the formation of a threedimensional network.

Keywords

, single, crystal X, ray study; T = 298 K; mean (C–C) = 0.003 A° ; R factor = 0.038; wR factor = 0.094; data, to, parameter ratio = 17.1.
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@article{paperid:1019328,
author = {Hossein Aghabozorg and Shabnam Ahmadvand and Mirzaei Shahrabi, Masoud and Hamid Reza Khavasi},
title = {Bis(9-aminoacridinium) bis(pyridine-2,6-dicarboxylato)cuprate(II) trihydrate},
journal = {Acta Crystallographica Section E: Structure Reports Online},
year = {2010},
volume = {66},
number = {66},
month = {September},
issn = {1600-5368},
pages = {1318--1319},
numpages = {1},
keywords = {single-crystal X-ray study; T = 298 K; mean (C–C) = 0.003 A° ; R factor = 0.038; wR factor = 0.094; data-to-parameter ratio = 17.1.},
}

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%0 Journal Article
%T Bis(9-aminoacridinium) bis(pyridine-2,6-dicarboxylato)cuprate(II) trihydrate
%A Hossein Aghabozorg
%A Shabnam Ahmadvand
%A Mirzaei Shahrabi, Masoud
%A Hamid Reza Khavasi
%J Acta Crystallographica Section E: Structure Reports Online
%@ 1600-5368
%D 2010

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