Indian Journal of Chemistry, Section A, ( ISI ), Volume (50), No (50), Year (2011-1) , Pages (51-54)

Title : ( Three new inorganic-organic hybrid materials based on inorganic cluster, [(PO4)M12O36].nH2O (M = Mo, W) )

Authors: Mohammad Yousefi , Hossein Eshtiagh Hosseini , Masoud Mirzaei Shahrabi , Alireza Salimi , Mohsen Nikpour ,

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Three new inorganic-organic hybrid materials based on heteropolyoxometalates, [L-C6H14NO2]3[(PO4)Mo12O36].3H2O (1), [L-C5H10NO2]3[(PO4)W12O36].H2O (2), and [C2H7N2O]3[(PO4)W12O36].4H2O (3), where C6H14NO2, C5H10NO2, and C2H7N2O are protonated L-leucine, L-proline, and methyl urea, respectively, have been synthesized and structurally characterized by some physico-chemical methods. Elemental analyses, IR, Raman, mass, UV, and 1H NMR spectroscopies of the title hybrid materials indicate that there are van der Waals interactions between O atoms of the heteropolyoxometalates and water molecules, as well as the N and O atoms of the amino acids and methyl urea moieties. The molecular structures of synthesized hybrid materials contain discrete entities of L-leucinium, L-prolinium or methyluronium and water molecules that surround every [(PO4)M12O36]3- anion, over the extended crystalline network. The observed bands in Raman spectra of (2) and (3) demonstrate that the [(PO4)W12O36]3- anion retains its “Keggin structure”. At pH = 4 – 7, the characteristic bands of the Keggin anion [(PO4)M12O36]3−(M = Mo, W) appear at 210 and 260 nm in the UV spectra, respectively.

Keywords

, Polyoxometalates, Metalates, Hybrids, Inorganicorganic hybrids, Amino acids, L-Leucine, L-Proline, Methyl
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@article{paperid:1019335,
author = {Mohammad Yousefi and Eshtiagh Hosseini, Hossein and Mirzaei Shahrabi, Masoud and Salimi, Alireza and Mohsen Nikpour},
title = {Three new inorganic-organic hybrid materials based on inorganic cluster, [(PO4)M12O36].nH2O (M = Mo, W)},
journal = {Indian Journal of Chemistry, Section A},
year = {2011},
volume = {50},
number = {50},
month = {January},
issn = {0376-4710},
pages = {51--54},
numpages = {3},
keywords = {Polyoxometalates; Metalates; Hybrids; Inorganicorganic hybrids; Amino acids; L-Leucine; L-Proline; Methyl urea},
}

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%0 Journal Article
%T Three new inorganic-organic hybrid materials based on inorganic cluster, [(PO4)M12O36].nH2O (M = Mo, W)
%A Mohammad Yousefi
%A Eshtiagh Hosseini, Hossein
%A Mirzaei Shahrabi, Masoud
%A Salimi, Alireza
%A Mohsen Nikpour
%J Indian Journal of Chemistry, Section A
%@ 0376-4710
%D 2011

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