Title : ( Bis(2-amino-4-methylpyridinium) bis(pyridine-2,6-dicarboxylato) cuprateII )
Authors: Hossein Aghabozorg , Azadeh Mofidi Rouchi , Behrouz Notash , Masoud Mirzaei Shahrabi ,
Full TextAbstract
The asymmetric unit of the title compound, (C6H9N2)2- [Cu(C7H3NO4)2], contains half of a [Cu(pydc)2]2 (pydcH2 is pyridine-2,6-dicarboxylic acid) anion and one protonated 2- amino-4-methylpyridine (2a4mpH)+ counter-ion. The anion is a six-coordinated complex with a distorted CuN2O4 octahedral geometry around the CuII ion. N—H O and C— H O hydrogen bonds along with – contacts between the pyridine rings of the (2a4mpH)+ cations [centroid–centroid distance = 3.573 (2) A ° ] stabilize the crystal structure.
Keywords
, single, crystal X, ray study; T = 298 K; mean (C–C) = 0.004 A° ; R factor = 0.057; wR factor = 0.119; data, to, parameter ratio = 17.5.
@article{paperid:1019983,
author = {Hossein Aghabozorg and Azadeh Mofidi Rouchi and Behrouz Notash and Mirzaei Shahrabi, Masoud},
title = {Bis(2-amino-4-methylpyridinium) bis(pyridine-2,6-dicarboxylato) cuprateII},
journal = {Acta Crystallographica Section E: Structure Reports Online},
year = {2011},
volume = {67},
number = {67},
month = {January},
issn = {1600-5368},
pages = {189--189},
numpages = {0},
keywords = {single-crystal X-ray study; T = 298 K; mean (C–C) = 0.004 A°
;
R factor = 0.057; wR factor = 0.119; data-to-parameter ratio = 17.5.},
}
%0 Journal Article
%T Bis(2-amino-4-methylpyridinium) bis(pyridine-2,6-dicarboxylato) cuprateII
%A Hossein Aghabozorg
%A Azadeh Mofidi Rouchi
%A Behrouz Notash
%A Mirzaei Shahrabi, Masoud
%J Acta Crystallographica Section E: Structure Reports Online
%@ 1600-5368
%D 2011
