Title : ( catena-Poly[4,4´-bipyridinium [[tetraaqua(pyridine-2,6-dicarboxylato-k3O2,N,O6)cerate(III)]-µ-pyridine-2,6-dicarboxylato-k4O2:O2´,N,O6-[(pyridine-2,6-dicarboxylato-k3O2,N,O6)-cerate(III)]-µ-pyridine-2,6-dicarboxylato-k4O2,N,O6:O6´] pentahydrate] )
Authors: Hossein Aghabozorg , Sara Omidvar , Masoud Mirzaei Shahrabi , Behrouz Notash ,
Full TextAbstract
The title compound, {(C10H10N2)[Ce2(C7H3NO4)4(H2O)4]- 5H2O}n, is composed of a one-dimensional anionic complex, a doubly protonated 4,40-bipyridine molecule as a counter-ion and five uncoordinated water molecules. The anion bears two nine-coordinate CeIII ions, each with a distorted tricapped trigonal–prismatic geometry. In the crystal, intermolecular C—H O, N—H O andO—H O hydrogen bonds, as well as – interactions with centroid–centroid distances of 3.514 (3) A ° connect the various components into a supramolecular structure.
Keywords
, single, crystal X, ray study; T = 150 K; mean (C–C) = 0.006 A° ; R factor = 0.045; wR factor = 0.120; data, to, parameter ratio = 16.6.
@article{paperid:1019986,
author = {Hossein Aghabozorg and Sara Omidvar and Mirzaei Shahrabi, Masoud and Behrouz Notash},
title = {catena-Poly[4,4´-bipyridinium [[tetraaqua(pyridine-2,6-dicarboxylato-k3O2,N,O6)cerate(III)]-µ-pyridine-2,6-dicarboxylato-k4O2:O2´,N,O6-[(pyridine-2,6-dicarboxylato-k3O2,N,O6)-cerate(III)]-µ-pyridine-2,6-dicarboxylato-k4O2,N,O6:O6´] pentahydrate]},
journal = {Acta Crystallographica Section E: Structure Reports Online},
year = {2011},
volume = {67},
number = {67},
month = {February},
issn = {1600-5368},
pages = {335--336},
numpages = {1},
keywords = {single-crystal X-ray study; T = 150 K; mean (C–C) = 0.006 A°
;
R factor = 0.045; wR factor = 0.120; data-to-parameter ratio = 16.6.},
}
%0 Journal Article
%T catena-Poly[4,4´-bipyridinium [[tetraaqua(pyridine-2,6-dicarboxylato-k3O2,N,O6)cerate(III)]-µ-pyridine-2,6-dicarboxylato-k4O2:O2´,N,O6-[(pyridine-2,6-dicarboxylato-k3O2,N,O6)-cerate(III)]-µ-pyridine-2,6-dicarboxylato-k4O2,N,O6:O6´] pentahydrate]
%A Hossein Aghabozorg
%A Sara Omidvar
%A Mirzaei Shahrabi, Masoud
%A Behrouz Notash
%J Acta Crystallographica Section E: Structure Reports Online
%@ 1600-5368
%D 2011
