Title : ( Synthesis, characterization and crystal structures of mononuclear Zinc(II) dichloride complexes with 2,3,5,6-tetra(2-pyridyl)pyrazine )
Authors: S. Jamil. A. Fatemi , Amir SHokooh Saljooghi , M. Babaie ,
Full TextAbstract
Tppz (2,3,5,6-tetrakis(2-pyridyl)pyrazine) complexes [Zn(tppz)Cl2] have been synthesized and characterized by elemental analyses, IR, 1H NMR, cyclic voltammetry and electronic spectral studies. Solid state structures of complex have been determined by single-crystal X-ray crystallography. The structural determination shows that the mononuclear Zn(II) complex, [Zn(tppz)Cl2], is a 1D coordination polymer. Also an ORTEP drawing of [Zn(tppz)Cl2] shows that the coordination geometry around the Zn(II) center is slightly distorted from regular square-based pyramidal. Crystal data for [ZnCl2(C24H16N6)]: Triclinic, , a = 10.171 (2) Å, b = 10.3550 (13) Å, c = 12.239 (2) Å, α = 64.839 (9)o, β = 85.736 (8)o, γ = 77.842 (10)o, V = 1140.3 (4) Å3, Z = 2.
Keywords
, X-ray crystallography; Zinc complex; 2, 3, 5, 6-tetrakis(2-pyridyl)pyrazine (tppz); Cyclic voltammetry
@inproceedings{paperid:1020440,
author = {S. Jamil. A. Fatemi and SHokooh Saljooghi, Amir and M. Babaie},
title = {Synthesis, characterization and crystal structures of mononuclear Zinc(II) dichloride complexes with 2,3,5,6-tetra(2-pyridyl)pyrazine},
booktitle = {12th Iranian Inorganic Chemistry Conference (IICC12)},
year = {2010},
location = {رشت (گیلان), IRAN},
keywords = {X-ray crystallography; Zinc complex; 2;3;5;6-tetrakis(2-pyridyl)pyrazine (tppz); Cyclic voltammetry},
}
%0 Conference Proceedings
%T Synthesis, characterization and crystal structures of mononuclear Zinc(II) dichloride complexes with 2,3,5,6-tetra(2-pyridyl)pyrazine
%A S. Jamil. A. Fatemi
%A SHokooh Saljooghi, Amir
%A M. Babaie
%J 12th Iranian Inorganic Chemistry Conference (IICC12)
%D 2010
