Title : ( Bis(8-hydroxy-2- methylquinolinium) bis(pyridine-2,6-dicarboxylato)-cuprate(II) methanol monosolvate )
Authors: H. Aghabozorg , A. Gholizadeh , Masoud Mirzaei Shahrabi , B. Notash ,
Full TextAbstract
The title compound, (C10H10NO)2[Cu(C7H3NO4)2]CH3OH- H2O was prepared by the reaction of copper(II) nitrate hexahydrate, 8-hydroxy-2-methylquinoline, and pyridine-2,6- dicarboxylic acid in a 1:2:2 molar ratio in an aqueous solution. The geometry of the resulting CuN2O4 coordination can be described as distorted octahedral. In the crystal, there are several intermolecular O—H O, N—H O and C—H O hydrogen bonds. An intramolecular N—H O hydrogen bond occurs in one of the cations. Considerable – stacking interactions are also observed between the aromatic rings of the cations, with centroid–centroid distances of 3.4567 (13), 3.5342 (14), 3.6941 (14) and 3.4568 (13) A ° . These non-covalent interactions connect the components, forming a threedimensional supramolecular structure.
Keywords
, single, crystal X, ray study; T = 298 K; mean (C–C) = 0.003 A° ; R factor = 0.038; wR factor = 0.109; data, to, parameter ratio = 18.2.
@article{paperid:1020552,
author = {H. Aghabozorg and A. Gholizadeh and Mirzaei Shahrabi, Masoud and B. Notash},
title = {Bis(8-hydroxy-2- methylquinolinium) bis(pyridine-2,6-dicarboxylato)-cuprate(II) methanol monosolvate},
journal = {Acta Crystallographica Section E: Structure Reports Online},
year = {2011},
volume = {67},
number = {67},
month = {February},
issn = {1600-5368},
pages = {379--380},
numpages = {1},
keywords = {single-crystal X-ray study; T = 298 K; mean (C–C) = 0.003 A°
;
R factor = 0.038; wR factor = 0.109; data-to-parameter ratio = 18.2.},
}
%0 Journal Article
%T Bis(8-hydroxy-2- methylquinolinium) bis(pyridine-2,6-dicarboxylato)-cuprate(II) methanol monosolvate
%A H. Aghabozorg
%A A. Gholizadeh
%A Mirzaei Shahrabi, Masoud
%A B. Notash
%J Acta Crystallographica Section E: Structure Reports Online
%@ 1600-5368
%D 2011
