Title : ( Bis(1-methyl-4-oxoimidazolidin-2- iminium) diaquabis(pyridine-2,4-dicarboxylato-k2N,O2)zincate(II) dihydrate )
Authors: H. Aghabozorg , F. Jafarbak , Masoud Mirzaei Shahrabi , B. Notash ,
Full TextAbstract
In the title compound, (C4H8N3O)2[Zn(C7H3NO4)2(H2O)2]- 2H2O, the ZnII ion is six-coordinated in a distorted octahedral geometry by two pyridine-2,4-dicarboxylate (pydc) ligands in the equatorial plane and two water molecules in the axial positions. The pydc ligands act as bidentate chelating ligands through one carboxylate O atom and the pyridine N atom. Intermolecular N—H O, O—H O and weak C—H O hydrogen bonds stabilize the crystal structure.
Keywords
, single, crystal X, ray study; T = 298 K; mean (C–C) = 0.002 A° ; R factor = 0.033; wR factor = 0.090; data, to, parameter ratio = 16.8
@article{paperid:1021156,
author = {H. Aghabozorg and F. Jafarbak and Mirzaei Shahrabi, Masoud and B. Notash},
title = {Bis(1-methyl-4-oxoimidazolidin-2- iminium) diaquabis(pyridine-2,4-dicarboxylato-k2N,O2)zincate(II) dihydrate},
journal = {Acta Crystallographica Section E: Structure Reports Online},
year = {2011},
volume = {67},
number = {67},
month = {March},
issn = {1600-5368},
pages = {435--436},
numpages = {1},
keywords = {single-crystal X-ray study; T = 298 K; mean (C–C) = 0.002 A°
;
R factor = 0.033; wR factor = 0.090; data-to-parameter ratio = 16.8},
}
%0 Journal Article
%T Bis(1-methyl-4-oxoimidazolidin-2- iminium) diaquabis(pyridine-2,4-dicarboxylato-k2N,O2)zincate(II) dihydrate
%A H. Aghabozorg
%A F. Jafarbak
%A Mirzaei Shahrabi, Masoud
%A B. Notash
%J Acta Crystallographica Section E: Structure Reports Online
%@ 1600-5368
%D 2011
