Inorganic Chemistry Communications, ( ISI ), Volume (12), No (12), Year (2009-1) , Pages (195-197)

Title : ( Synthesis, Structure and Analysis of Intermolecular Interactions of Organic-inorganic Hybrid Compound Based on Anderson-type Polyoxometalates and Piperazine )

Authors: X.D. Yang , Y.-G. Chen , Masoud Mirzaei Shahrabi , Alireza Salimi , F. Yao ,

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Abstract

A new organic–inorganic hybrid compound based on Anderson-B polyoxomolybdates, (H2Pz)5[Al(OH)6- Mo6O18]2(SO4)2  16H2O (1) (Pz = piperazine) was synthesized and characterized by elemental analysis, IR, and single-crystal X-ray diffraction. The anions in 1 are stacked into a layer in [200] plane by hydrogen bonds of water molecules and van der Waas force, and between the layers are the sulfate ions and piperazine ions. The hydroxyl hydrogen atoms of Anderson-B anion make the anion be hydrogen bond donor. And the sulfate anion is the hydrogen bond acceptor. The analysis of the Hirshfeld surfaces of 1 makes us understand the type and nature of intermolecular interactions in the crystal in a visual manner.

Keywords

, Polyoxometalates Anderson, B anion Crystal structure Hirshfeld surface analysis Intermolecular interactions
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@article{paperid:1021160,
author = {X.D. Yang and Y.-G. Chen and Mirzaei Shahrabi, Masoud and Salimi, Alireza and F. Yao},
title = {Synthesis, Structure and Analysis of Intermolecular Interactions of Organic-inorganic Hybrid Compound Based on Anderson-type Polyoxometalates and Piperazine},
journal = {Inorganic Chemistry Communications},
year = {2009},
volume = {12},
number = {12},
month = {January},
issn = {1387-7003},
pages = {195--197},
numpages = {2},
keywords = {Polyoxometalates Anderson-B anion Crystal structure Hirshfeld surface analysis Intermolecular interactions},
}

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%0 Journal Article
%T Synthesis, Structure and Analysis of Intermolecular Interactions of Organic-inorganic Hybrid Compound Based on Anderson-type Polyoxometalates and Piperazine
%A X.D. Yang
%A Y.-G. Chen
%A Mirzaei Shahrabi, Masoud
%A Salimi, Alireza
%A F. Yao
%J Inorganic Chemistry Communications
%@ 1387-7003
%D 2009

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