Title : ( Synthesis, structure and analysis of intermolecular interactions of organic–inorganic hybrid compound based on Anderson-type polyoxometalates and piperazine )
Authors: X.D. Yang , Y.-G. Chen , Masoud Mirzaei Shahrabi , Alireza Salimi , F. Yao ,
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Abstract
A new organic–inorganic hybrid compound based on Anderson-B polyoxomolybdates, (H2Pz)5[Al(OH)6- Mo6O18]2(SO4)2 16H2O (1) (Pz = piperazine) was synthesized and characterized by elemental analysis, IR, and single-crystal X-ray diffraction. The anions in 1 are stacked into a layer in [200] plane by hydrogen bonds of water molecules and van der Waas force, and between the layers are the sulfate ions and piperazine ions. The hydroxyl hydrogen atoms of Anderson-B anion make the anion be hydrogen bond donor. And the sulfate anion is the hydrogen bond acceptor. The analysis of the Hirshfeld surfaces of 1 makes us understand the type and nature of intermolecular interactions in the crystal in a visual manner.
Keywords
, Polyoxometalates Anderson, B anion Crystal structure Hirshfeld surface analysis Intermolecular interactions
@article{paperid:1021160,
author = {X.D. Yang and Y.-G. Chen and Mirzaei Shahrabi, Masoud and Salimi, Alireza and F. Yao},
title = {Synthesis, structure and analysis of intermolecular interactions of organic–inorganic hybrid compound based on Anderson-type polyoxometalates and piperazine},
journal = {Inorganic Chemistry Communications},
year = {2009},
volume = {12},
number = {3},
month = {January},
issn = {1387-7003},
pages = {195--197},
numpages = {2},
keywords = {Polyoxometalates
Anderson-B anion
Crystal structure
Hirshfeld surface analysis
Intermolecular interactions},
}
%0 Journal Article
%T Synthesis, structure and analysis of intermolecular interactions of organic–inorganic hybrid compound based on Anderson-type polyoxometalates and piperazine
%A X.D. Yang
%A Y.-G. Chen
%A Mirzaei Shahrabi, Masoud
%A Salimi, Alireza
%A F. Yao
%J Inorganic Chemistry Communications
%@ 1387-7003
%D 2009
