Title : ( 2D-Network of Inorganic-Organic Hybrid Material Built on Keggin Type Polyoxometallate and Amino Acid: [L-C2H6NO2]3[(PO4) Mo12O36].5H2O )
Authors: Mohammad Hasan Alizadeh Ghanad , Masoud Mirzaei Shahrabi , H. Razavi ,
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Abstract
A new inorganic–organic hybrid material based on polyoxometallate, [L-C2H6NO2]3[(PO4)Mo12O36]5H2O, has been successfully synthesized and characterized by single-crystal X-ray analysis, elemental analysis, infrared and ultraviolet spectroscopy, proton nuclear magnetic resonance and differential thermal analysis techniques. The title compound crystallizes in the monoclinic space group, P21/c, with a = 12.4938 (8) A ° , b = 19.9326 (12) A ° , c = 17.9270 (11) A ° , b = 102.129 (1)8, V = 4364.8 (5) A ° 3, Z = 4 and R1ðwR2Þ = 0.0513, 0.0877. The most remarkable structural feature of this hybrid can be described as two-dimensional inorganic infinite plane-like (2D/1 [(PO4)Mo12O36]3) which forming via weak Van der Waals interactions along the z axis. The characteristic band of the Keggin anion [(PO4)Mo12O36]3 appears at 210 nm in the UV spectrum. Thermal analysis indicates that the Keggin anion skeleton begins to decompose at 520 8C.
Keywords
, Inorganic compound; Organic compound; Chemical synthesis; X, ray diffraction; Infrared spectroscopy; Crystal structure
@article{paperid:1021168,
author = { Alizadeh Ghanad, Mohammad Hasan and Mirzaei Shahrabi, Masoud and H. Razavi},
title = {2D-Network of Inorganic-Organic Hybrid Material Built on Keggin Type Polyoxometallate and Amino Acid: [L-C2H6NO2]3[(PO4) Mo12O36].5H2O},
journal = {Materials Research Bulletin},
year = {2007},
volume = {43},
number = {43},
month = {April},
issn = {0025-5408},
pages = {546--555},
numpages = {9},
keywords = {Inorganic compound; Organic compound; Chemical synthesis; X-ray diffraction; Infrared spectroscopy; Crystal structure},
}
%0 Journal Article
%T 2D-Network of Inorganic-Organic Hybrid Material Built on Keggin Type Polyoxometallate and Amino Acid: [L-C2H6NO2]3[(PO4) Mo12O36].5H2O
%A Alizadeh Ghanad, Mohammad Hasan
%A Mirzaei Shahrabi, Masoud
%A H. Razavi
%J Materials Research Bulletin
%@ 0025-5408
%D 2007
