Title : ( S-allyl-3-(2-pyridyl-methylene)dithiocarbazate ligand and its manganese(II), cobalt(III) and nickel(II) complexes )
Authors: Reza Takjoo , Roberto Centore , Mohammad Hakimi , S. Ali Beyramabadi , Ali Morsali ,
Full TextAbstract
A new NNS tridentate ligand, S-allyl-3-(2-pyridyl-methylene)dithiocarbazate (HL) and its Mn(L)2, [Co(L)2]NO3 and Ni(L)2 complexes have been prepared and characterized with usual methods. Single crystal X-ray analysis shows that bis-chelate complexes have a distorted octahedral geometry. Molecular geometry optimization, atomic charges distribution and bond analysis of the ligand and complexes have been performed using DFT with the B3LYP functional.
Keywords
, NNS donor ligand; Schiff base; S, allyl dithiocarbazate; Metal complexes; Crystal structure; DFT
@article{paperid:1022020,
author = {Takjoo, Reza and Roberto Centore and Mohammad Hakimi and S. Ali Beyramabadi and Ali Morsali},
title = {S-allyl-3-(2-pyridyl-methylene)dithiocarbazate ligand and its manganese(II), cobalt(III) and nickel(II) complexes},
journal = {Inorganica Chimica Acta},
year = {2011},
volume = {371},
number = {1},
month = {May},
issn = {0020-1693},
pages = {36--41},
numpages = {5},
keywords = {NNS donor ligand; Schiff base; S-allyl dithiocarbazate; Metal complexes; Crystal structure; DFT},
}
%0 Journal Article
%T S-allyl-3-(2-pyridyl-methylene)dithiocarbazate ligand and its manganese(II), cobalt(III) and nickel(II) complexes
%A Takjoo, Reza
%A Roberto Centore
%A Mohammad Hakimi
%A S. Ali Beyramabadi
%A Ali Morsali
%J Inorganica Chimica Acta
%@ 0020-1693
%D 2011
