Journal of Industrial and Engineering Chemistry, ( ISI ), Volume (17), No (3), Year (2011-7) , Pages (596-602)

Title : ( Size dependence on reduction kinetic of iron based Fischer–Tropsch catalyst )

Authors: Ali Nakhaei Pour , Mohammad Reza Housaindokht , Seyed Mehdi Kamali Shahri ,

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Abstract

Catalyst structure has a significant influence on its kinetic behavior. In this work, effect of nanoparticle size on reduction kinetics of iron FTS catalyst, [0] has been studied. Fe/Cu/La catalysts were prepared via bulk precipitation and microemulsion methods to produce a series of iron oxides with different particle size. In microemulsion method, the catalyst particle size was changed with type of surfactant such as SDS, Triton x-100, and SDBS. Size dependence on reduction rate constant (kr) was evaluated using the formation and growth of nuclei model (3D). The results showed that when the catalyst particle size increased, the reduction rate of iron catalyst decreased. A value of 3.11 nm and 0.53 h−1were obtained for η parameter and size independent part of reduction rate constant (k∞), which are consistent with the values reported in literatures

Keywords

, Fischer–Tropsch synthesis; Iron, based catalyst; Catalyst reduction; Microemulsion
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@article{paperid:1022025,
author = {Nakhaei Pour, Ali and Housaindokht, Mohammad Reza and Seyed Mehdi Kamali Shahri},
title = {Size dependence on reduction kinetic of iron based Fischer–Tropsch catalyst},
journal = {Journal of Industrial and Engineering Chemistry},
year = {2011},
volume = {17},
number = {3},
month = {July},
issn = {1226-086X},
pages = {596--602},
numpages = {6},
keywords = {Fischer–Tropsch synthesis; Iron-based catalyst; Catalyst reduction; Microemulsion},
}

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%0 Journal Article
%T Size dependence on reduction kinetic of iron based Fischer–Tropsch catalyst
%A Nakhaei Pour, Ali
%A Housaindokht, Mohammad Reza
%A Seyed Mehdi Kamali Shahri
%J Journal of Industrial and Engineering Chemistry
%@ 1226-086X
%D 2011

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