12th Iranian Inorganic Chemistry Conference , 2010-09-15

Title : ( Synthesis and Characterization of Two New Supramolecular Coordination Compounds Including Pyridin- 3,5-dicarboxylic acid Ligand and CoII /NiII atoms In the Presence of 9-Aminoacridinium Spacer )

Authors: Somayeh Sanaei , Hossein Eshtiagh Hosseini , Masoud Mirzaei Shahrabi , Mehrdad Pourayoubi ,

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Two new coordination compounds were obtained by the reaction of pyridine- 3,5-dicarboxylic acid ligand and CoII /NiII in the presence of 9-amino acridinium spacer in the solution phase. The titled compounds were characterized by elemental analyses, IR and 1H NMR spectroscopies. They are resulted from proton transfer between pyridine 3,5 dicarboxylic acid and 9-amino acridine and then adding of metallic salts such as cobaltII acetate and nickelII chloride lead to the formation of corresponding supramolecularly coordination compounds. The pyridin-3,5- dicarboxylic acid as a carboxylate function derivatives has attracted much interest in the coordination chemistry. Indeed, pyridine- 3,5- dicarboxylic acid and 9-amino acridine used here can form a good proton donoracceptor system. Many aspects of these two compounds such as their solution phase studies and single crystal X-ray diffraction remains to be investigated as we intend to do in the near future.

Keywords

, Nickel, Proton transfer mechanism, Nickel, Supramolecular
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@inproceedings{paperid:1022272,
author = {Somayeh Sanaei and Eshtiagh Hosseini, Hossein and Mirzaei Shahrabi, Masoud and Pourayoubi, Mehrdad},
title = {Synthesis and Characterization of Two New Supramolecular Coordination Compounds Including Pyridin- 3,5-dicarboxylic acid Ligand and CoII /NiII atoms In the Presence of 9-Aminoacridinium Spacer},
booktitle = {12th Iranian Inorganic Chemistry Conference},
year = {2010},
location = {گیلان, IRAN},
keywords = {Nickel;Proton transfer mechanism;Nickel;Supramolecular compound},
}

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%0 Conference Proceedings
%T Synthesis and Characterization of Two New Supramolecular Coordination Compounds Including Pyridin- 3,5-dicarboxylic acid Ligand and CoII /NiII atoms In the Presence of 9-Aminoacridinium Spacer
%A Somayeh Sanaei
%A Eshtiagh Hosseini, Hossein
%A Mirzaei Shahrabi, Masoud
%A Pourayoubi, Mehrdad
%J 12th Iranian Inorganic Chemistry Conference
%D 2010

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