Acta Crystallographica Section E: Structure Reports Online, ( ISI ), Volume (67), No (67), Year (2011-6) , Pages (1411-1412)

Title : ( Bis(9-aminoacridinium)bis(pyridine-2,6-dicarboxylato-κ3O2,N,O6)manganate(II)trihydrate )

Authors: Hossein Eshtiagh Hosseini , Masoud Mirzaei Shahrabi , ehsan eidi , zakieh yousefie , Kresˇimir Molcˇanov ,

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The asymmetric unit of the title compound, (C13H11N2)2- [Mn(C7H3NO4)2]3H2O, consists of a discrete mononuclear [Mn(2,6-pydc)2]2 anionic complex (2,6-pydc is pyridine-2,6- dicarboxylate) associated with two 9-aminoacridinium counter-ions for neutralization of charge and three uncoordinated water molecules. The MnII atom is six-coordinated by (2,6-pydc)2 anions in a tridentate fashion and is at the centre of a distorted octahedron formed by the MnO4N2 bonding set. In the crystal, various intermolecular interactions between different moieties can be found, such as different kinds of hydrogen bonds, offset or slipped – [centroid–centroid distances in the range 3.3704 (12) to 3.8674 (13)A˚ ] and C O   [3.563 A ˚ ] interactions, which lead to the formation of a three-dimensional supramolecular network.

Keywords

, single, crystal X, ray study; T = 293 K; mean (C–C) = 0.003 A° ; R factor = 0.038; wR factor = 0.114; data, to, parameter ratio =
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@article{paperid:1023552,
author = {Eshtiagh Hosseini, Hossein and Mirzaei Shahrabi, Masoud and Eidi, Ehsan and Yousefie, Zakieh and Kresˇimir Molcˇanov},
title = {Bis(9-aminoacridinium)bis(pyridine-2,6-dicarboxylato-κ3O2,N,O6)manganate(II)trihydrate},
journal = {Acta Crystallographica Section E: Structure Reports Online},
year = {2011},
volume = {67},
number = {67},
month = {June},
issn = {1600-5368},
pages = {1411--1412},
numpages = {1},
keywords = {single-crystal X-ray study; T = 293 K; mean (C–C) = 0.003 A° ; R factor = 0.038; wR factor = 0.114; data-to-parameter ratio = 13.3.},
}

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%0 Journal Article
%T Bis(9-aminoacridinium)bis(pyridine-2,6-dicarboxylato-κ3O2,N,O6)manganate(II)trihydrate
%A Eshtiagh Hosseini, Hossein
%A Mirzaei Shahrabi, Masoud
%A Eidi, Ehsan
%A Yousefie, Zakieh
%A Kresˇimir Molcˇanov
%J Acta Crystallographica Section E: Structure Reports Online
%@ 1600-5368
%D 2011

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