Title : ( Diphenyl [(S)-1-phenylpropanamido]-phosphate )
Authors: Fahimeh Sabbaghi , Mehrdad Pourayoubi , monireh negari , Marek Nečas ,
Full TextAbstract
The title compound, C21H22NO3P, was synthesized from the reaction of (C6H5O)2P(O)(Cl) and S-1-phenylpropylamine (1:2 mole ratio) at 273 K, followed by removal of the S-1- phenylpropylamine hydrochloride by-product by dissolving in H2O. The P atom is located in a distorted tetrahedral environment. The bond angles at the P atom vary from 99.51 (12) to 116.68 (12)°. The sp2 character of the N atom is reflected by the C—N—P angle [120.9 (2)°]. The P=O group and the N—H unit adopt an anti orientation with respect to one another. In the crystal, adjacent molecules are linked via N—H...O(P) hydrogen bonds into a one-dimensional arrangement running parallel to the a axis.
Keywords
, single, crystal X, ray study; T = 120 K; mean σ(C–C) = 0.005 Å; R factor = 0.052; wR factor = 0.089; data, to, parameter ratio = 12.6.
@article{paperid:1023910,
author = {Fahimeh Sabbaghi and Pourayoubi, Mehrdad and Negari, Monireh and Marek Nečas},
title = {Diphenyl [(S)-1-phenylpropanamido]-phosphate},
journal = {Acta Crystallographica Section E: Structure Reports Online},
year = {2011},
volume = {67},
number = {9},
month = {September},
issn = {1600-5368},
pages = {2512--2512},
numpages = {0},
keywords = {single-crystal X-ray study; T = 120 K; mean σ(C–C) = 0.005 Å;
R factor = 0.052; wR factor = 0.089; data-to-parameter ratio = 12.6.},
}
%0 Journal Article
%T Diphenyl [(S)-1-phenylpropanamido]-phosphate
%A Fahimeh Sabbaghi
%A Pourayoubi, Mehrdad
%A Negari, Monireh
%A Marek Nečas
%J Acta Crystallographica Section E: Structure Reports Online
%@ 1600-5368
%D 2011
