Title : ( N,N--Di-tert-butyl-N--(2-chloroacetyl)-phosphoric triamide )
Authors: Mehrdad Pourayoubi , behrouz elahi , Masood Parvez ,
Full TextAbstract
The P atom in the title molecule, C10H23ClN3O2P, has a distorted tetrahedral coordination. In the C(O)NHP(O) unit, which has syn-oriented phosphoryl and N—H groups, the P—N bond of 1.703 (2) Å is longer and the O—P—N angle of 103.86 (7)° is contracted compared with the respective values in the two P(O)NHC(CH3)3 units [P—N = 1.632 (2) and 1.624 (2) Å; O—P—N = 116.80 (8) and 115.32 (8)°]. In the crystal, each molecule is hydrogen bonded to two adjacent molecules via N—H…O hydrogen bonds, forming a linear sequence of alternating R22(8) and R22(12)/R21(6)-fused rings along [010]. The O atom of the carbonyl group acts as a double H-atom acceptor.
Keywords
, single, crystal X, ray study; T = 173 K; mean σ(C–C) = 0.003 Å; R factor = 0.043; wR factor = 0.103; data, to, parameter ratio = 20.2
@article{paperid:1023979,
author = {Pourayoubi, Mehrdad and Elahi, Behrouz and Masood Parvez},
title = {N,N--Di-tert-butyl-N--(2-chloroacetyl)-phosphoric triamide},
journal = {Acta Crystallographica Section E: Structure Reports Online},
year = {2011},
volume = {67},
number = {11},
month = {November},
issn = {1600-5368},
pages = {2848--2848},
numpages = {0},
keywords = {single-crystal X-ray study; T = 173 K; mean σ(C–C) = 0.003 Å; R factor = 0.043; wR factor = 0.103; data-to-parameter ratio = 20.2},
}
%0 Journal Article
%T N,N--Di-tert-butyl-N--(2-chloroacetyl)-phosphoric triamide
%A Pourayoubi, Mehrdad
%A Elahi, Behrouz
%A Masood Parvez
%J Acta Crystallographica Section E: Structure Reports Online
%@ 1600-5368
%D 2011
