Title : ( N,N,N\',N\'-Tetraethyl-N\"-(2-fluorobenzoyl)phosphoric triamide )
Authors: Atekeh Tarahhomi , Mehrdad Pourayoubi , Arnold L. Rheingold , James A. Golen ,
Full TextAbstract
In the title compound, C15H25FN3O2P, the phosphoryl group is in an anti and syn orientation to the C=O and N—H groups, respectively. The P atom is in a distorted tetrahedral environment. One of the ethyl groups is disordered over two sets of sites with refined occupancies of 0.755 (6) and 0.245 (6). In addition, the F atom was refined as disordered with occupancies fixed at 0.9 and 0.1. This disorder corresponds to a rotation of approximately 180° of the fluorobenzene ring about its connecting C—C bond. In the crystal, pairs of intermolecular N—H…O(=P) hydrogen bonds form centrosymmetric dimers.
Keywords
, single, crystal X, ray study; T = 100 K; mean σ(C–C) = 0.003 Å; disorder in main residue; R factor = 0.047; wR factor = 0.122; data, to, parameter ratio = 15.9
@article{paperid:1023997,
author = {Tarahhomi, Atekeh and Pourayoubi, Mehrdad and Arnold L. Rheingold and James A. Golen},
title = {N,N,N\',N\'-Tetraethyl-N\"-(2-fluorobenzoyl)phosphoric triamide},
journal = {Acta Crystallographica Section E: Structure Reports Online},
year = {2011},
volume = {67},
number = {10},
month = {October},
issn = {1600-5368},
pages = {2643--2643},
numpages = {0},
keywords = {single-crystal X-ray study; T = 100 K; mean σ(C–C) = 0.003 Å; disorder in main residue; R factor = 0.047; wR factor = 0.122; data-to-parameter ratio = 15.9},
}
%0 Journal Article
%T N,N,N\',N\'-Tetraethyl-N\"-(2-fluorobenzoyl)phosphoric triamide
%A Tarahhomi, Atekeh
%A Pourayoubi, Mehrdad
%A Arnold L. Rheingold
%A James A. Golen
%J Acta Crystallographica Section E: Structure Reports Online
%@ 1600-5368
%D 2011
