Title : ( N,N--Bis(2-chlorobenzyl)-N--(2,2,2-trichloroacetyl)phosphoric triamide )
Authors: Mehrdad Pourayoubi , hassan fadaei , Masood Parvez ,
Full TextAbstract
The P atom in the title compound, C16H15Cl5N3O2P, exhibits a tetrahedral coordination geometry and the phosphoryl and carbonyl groups are anti with respect to one another. The dihedral angle between the benzene rings is 44.90 (15)°. One of the 2-chlorobenzylamido fragments is disordered over two sets of sites with occupancies of 0.8823 (17) and 0.1177 (17). In the crystal, adjacent molecules are linked via N—H…O(P) and N—H…O(C) hydrogen bonds into an extended chain running parallel to the a axis.
Keywords
, single, crystal X, ray study; T = 173 K; mean σ(C–C) = 0.005 Å; disorder in main residue; R factor = 0.053; wR factor = 0.129; data, to, parameter ratio = 18.9
@article{paperid:1024001,
author = {Pourayoubi, Mehrdad and Fadaei, Hassan and Masood Parvez},
title = {N,N--Bis(2-chlorobenzyl)-N--(2,2,2-trichloroacetyl)phosphoric triamide},
journal = {Acta Crystallographica Section E: Structure Reports Online},
year = {2011},
volume = {67},
number = {8},
month = {August},
issn = {1600-5368},
pages = {2046--2046},
numpages = {0},
keywords = {single-crystal X-ray study; T = 173 K; mean σ(C–C) = 0.005 Å; disorder in main residue; R factor = 0.053; wR factor = 0.129; data-to-parameter ratio = 18.9},
}
%0 Journal Article
%T N,N--Bis(2-chlorobenzyl)-N--(2,2,2-trichloroacetyl)phosphoric triamide
%A Pourayoubi, Mehrdad
%A Fadaei, Hassan
%A Masood Parvez
%J Acta Crystallographica Section E: Structure Reports Online
%@ 1600-5368
%D 2011
