Title : ( N,N--Dicyclohexyl-N--(2,6-difluorobenzoyl)-N,N--dimethylphosphoric triamide )
Authors: Mehrdad Pourayoubi , Atekeh Tarahhomi , Arnold L. Rheingold , James A. Golen ,
Full TextAbstract
In the title molecule, C21H32F2N3O2P, the P=O and N—H groups are syn with respect to each other, and the P atom is bonded in a distorted tetrahedral environment. The phosphoryl group adopts an anti orientation with respect to the carbonyl group. The angles at the tertiary N atoms (with bond angle sums of 358.4 and 357.0°) confirm their sp2 character. In the crystal, inversion dimers linked by pairs of N—H…O hydrogen bonds generate R22(8) loops.
Keywords
, single, crystal X, ray study; T = 100 K; mean σ(C–C) = 0.002 Å; R factor = 0.037; wR factor = 0.097; data, to, parameter ratio = 18.9
@article{paperid:1024069,
author = {Pourayoubi, Mehrdad and Tarahhomi, Atekeh and Arnold L. Rheingold and James A. Golen},
title = {N,N--Dicyclohexyl-N--(2,6-difluorobenzoyl)-N,N--dimethylphosphoric triamide},
journal = {Acta Crystallographica Section E: Structure Reports Online},
year = {2011},
volume = {67},
number = {11},
month = {November},
issn = {1600-5368},
pages = {3027--3027},
numpages = {0},
keywords = {single-crystal X-ray study; T = 100 K; mean σ(C–C) = 0.002 Å; R factor = 0.037; wR factor = 0.097; data-to-parameter ratio = 18.9},
}
%0 Journal Article
%T N,N--Dicyclohexyl-N--(2,6-difluorobenzoyl)-N,N--dimethylphosphoric triamide
%A Pourayoubi, Mehrdad
%A Tarahhomi, Atekeh
%A Arnold L. Rheingold
%A James A. Golen
%J Acta Crystallographica Section E: Structure Reports Online
%@ 1600-5368
%D 2011
