Title : ( N,N-Dimethyl-N-,N---diphenylphosphoric triamide )
Authors: Mehrdad Pourayoubi , Mohammad Yousefi , Farnaz Eslami , Arnold L. Rheingold , Chao Chen ,
Full TextAbstract
In the title compound, C14H18N3OP, a crystallographic mirror plane bisects the molecule (the C,N,C atoms of the dimethylamido moiety and the P=O unit lie on the mirror plane). The P atom has a distorted tetrahedral geometry; the bond angles at P are in the range 98.98 (11)–115.28 (7)°. In the crystal, the O atom of the P=O group acts as a double hydrogen-bond acceptor for two symmetry-equivalent N—H…O hydrogen bonds, building [001] chains containing R21(6) loops.
Keywords
, single, crystal X, ray study; T = 100 K; mean σ(C–C) = 0.003 Å; R factor = 0.028; wR factor = 0.084; data, to, parameter ratio = 12.2
@article{paperid:1024328,
author = {Pourayoubi, Mehrdad and Mohammad Yousefi and Farnaz Eslami and Arnold L. Rheingold and Chao Chen},
title = {N,N-Dimethyl-N-,N---diphenylphosphoric triamide},
journal = {Acta Crystallographica Section E: Structure Reports Online},
year = {2011},
volume = {67},
number = {12},
month = {December},
issn = {1600-5368},
pages = {3220--3220},
numpages = {0},
keywords = {single-crystal X-ray study; T = 100 K; mean σ(C–C) = 0.003 Å; R factor = 0.028; wR factor = 0.084; data-to-parameter ratio = 12.2},
}
%0 Journal Article
%T N,N-Dimethyl-N-,N---diphenylphosphoric triamide
%A Pourayoubi, Mehrdad
%A Mohammad Yousefi
%A Farnaz Eslami
%A Arnold L. Rheingold
%A Chao Chen
%J Acta Crystallographica Section E: Structure Reports Online
%@ 1600-5368
%D 2011
