Title : ( Structural aspects and solution behavior of metallosupramolecular compound of FeIII ion obtained by proton transfer )
Authors: Hossein Eshtiagh Hosseini , Masoud Mirzaei Shahrabi , zakieh yousefie , H. Puschmann , A. Shokrollahi , R. Aghaei ,
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Abstract
A supramolecular coordination compound of FeIII containing pyridine-2,6-dicarboxylic acid (pydcH2) and 2-aminopyrimidine (2-apym), (2-apymH)[Fe(pydc)2] 2H2O (1), was synthesized at normal conditions and characterized by elemental analysis, FTIR and UV spectroscopic methods, and X-ray crystallography. The crystallographic data of the compound show that it crystallizes in monoclinic lattice with space group P21/c. The constituent fragments of the compound were connected to each other by diverse intermolecular interactions such as hydrogen-bonding, – stacking, and ion pairing forming a supramolecular system. The solution studies show that there exist molecular aggregations in the solution compared with solid state. In the solution, ternary species are negligible but binary species such as ML2 and ML2H are present (L is referred to pydcH2 moiety).
Keywords
, Iron; Pyridine-2, 6-dicarboxylic acid; 2-Aminopyrimidine; Supramolecular chemistry; Solution studies
@article{paperid:1024495,
author = {Eshtiagh Hosseini, Hossein and Mirzaei Shahrabi, Masoud and Yousefie, Zakieh and H. Puschmann and A. Shokrollahi and R. Aghaei},
title = {Structural aspects and solution behavior of metallosupramolecular compound of FeIII ion obtained by proton transfer},
journal = {Journal of Coordination Chemistry},
year = {2011},
volume = {64},
number = {22},
month = {November},
issn = {0095-8972},
pages = {3969--3979},
numpages = {10},
keywords = {Iron; Pyridine-2;6-dicarboxylic acid; 2-Aminopyrimidine; Supramolecular
chemistry; Solution studies},
}
%0 Journal Article
%T Structural aspects and solution behavior of metallosupramolecular compound of FeIII ion obtained by proton transfer
%A Eshtiagh Hosseini, Hossein
%A Mirzaei Shahrabi, Masoud
%A Yousefie, Zakieh
%A H. Puschmann
%A A. Shokrollahi
%A R. Aghaei
%J Journal of Coordination Chemistry
%@ 0095-8972
%D 2011
