Title : ( N,N--Dibenzyl-N,N--dimethyl-N---(2-phenylacetyl)phosphoric triamide )
Authors: Mehrdad Pourayoubi , samad shoghpour bayraq , Laura Torre-Fernández , Santiago Garcıa-Granda ,
Full TextAbstract
The P atom in the title molecule, C24H28N3O2P, is in a distorted tetrahedral P(=O)(N)(N)2 environment. The phosphoryl group and the NH unit adopt a syn orientation with respect to each other and the N atoms have sp2 character. The P—N bonds in the P(O)[N(CH3)(CH2C6H5)]2 unit are shorter than the P—N bond in the C(=O)NHP(=O) fragment. An intramolecular C—H…O hydrogen bond occurs. In the crystal, pairs of P=O…H—N hydrogen bonds form centrosymmetric dimers. C—H…O contacts are also observed. Four C atoms of two benzene rings are disordered over two alternative sites with an occupancy ratio of 0.523 (12):0.427 (12).
Keywords
, single, crystal X, ray study; T = 120 K; mean σ(C–C) = 0.006 Å; disorder in main residue; R factor = 0.073; wR factor = 0.216; data, to, parameter ratio = 14.8
@article{paperid:1024498,
author = {Pourayoubi, Mehrdad and Shoghpour Bayraq, Samad and Laura Torre-Fernández and Santiago Garcıa-Granda},
title = {N,N--Dibenzyl-N,N--dimethyl-N---(2-phenylacetyl)phosphoric triamide},
journal = {Acta Crystallographica Section E: Structure Reports Online},
year = {2011},
volume = {67},
number = {12},
month = {December},
issn = {1600-5368},
pages = {3425--3426},
numpages = {1},
keywords = {single-crystal X-ray study; T = 120 K; mean σ(C–C) = 0.006 Å; disorder in main residue; R factor = 0.073; wR factor = 0.216; data-to-parameter ratio = 14.8},
}
%0 Journal Article
%T N,N--Dibenzyl-N,N--dimethyl-N---(2-phenylacetyl)phosphoric triamide
%A Pourayoubi, Mehrdad
%A Shoghpour Bayraq, Samad
%A Laura Torre-Fernández
%A Santiago Garcıa-Granda
%J Acta Crystallographica Section E: Structure Reports Online
%@ 1600-5368
%D 2011
