Title : ( Decaaquabis(μ3-4-hydroxypyridine-2,6-dicarboxylato)bis(4-hydroxypyridine-2,6-dicarboxylato)tetramanganese(II) 3.34-hydrate: a new three-dimensional open metal-organic framework based on a tetranuclear MnII complex of chelidamic acid and undecameric stitching water clusters )
Authors: Masoud Mirzaei Shahrabi , V. Lippolis , Hossein Eshtiagh Hosseini , milad mahjoobizadeh ,
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Abstract
In this paper, the new [Mn~4~(cdaH)~4~^.^10H~2~O]^.^3.34H~2~O complex between Mn(II) and 4-Hydroxyoyridine-2,6-dicarboxylic acid (chelidamic acid, cdaH~3~) is described. It features tetranuclear Mn(II) clusters connected by (H~2~O)~10.34~ water clusters in the crystal packing. In the previously reported compound [Mn~2~(cdaH)~2~^.^4H~2~O]^.^4H~2~O (Ghosh <i>et al.</i>, 2005), (H~2~O)~14~ supramolecular clusters have been found responsible for the assembly of the final 3D MOF in the crystal lattice. The nuclearity of the metal complex as well as the nature of the metal ion are, therefore, important in determining the structural feature of the water cluster in the structure; in fact, the compound [Cd~4~(cdaH)~4~^.^10H~2~O]^.^4H~2~O (Das <i>et al.</i>, 2009) having the same stoichiometry and the same kind of tetranuclear metal cluster in the structure as the title compound, only features (H~2~O)~5~ clusters in the crystal lattice.
Keywords
[Mn4(C8H3NO5)4(H2O)10]·3.34H2O
@article{paperid:1024729,
author = {Mirzaei Shahrabi, Masoud and V. Lippolis and Eshtiagh Hosseini, Hossein and Mahjoobizadeh, Milad},
title = {Decaaquabis(μ3-4-hydroxypyridine-2,6-dicarboxylato)bis(4-hydroxypyridine-2,6-dicarboxylato)tetramanganese(II) 3.34-hydrate: a new three-dimensional open metal-organic framework based on a tetranuclear MnII complex of chelidamic acid and undecameric stitching water clusters},
journal = {Acta Crystallographica Section C: Structural Chemistry},
year = {2011},
volume = {68},
number = {1},
month = {December},
issn = {2053-2296},
pages = {7--11},
numpages = {4},
keywords = {[Mn4(C8H3NO5)4(H2O)10]·3.34H2O},
}
%0 Journal Article
%T Decaaquabis(μ3-4-hydroxypyridine-2,6-dicarboxylato)bis(4-hydroxypyridine-2,6-dicarboxylato)tetramanganese(II) 3.34-hydrate: a new three-dimensional open metal-organic framework based on a tetranuclear MnII complex of chelidamic acid and undecameric stitching water clusters
%A Mirzaei Shahrabi, Masoud
%A V. Lippolis
%A Eshtiagh Hosseini, Hossein
%A Mahjoobizadeh, Milad
%J Acta Crystallographica Section C: Structural Chemistry
%@ 2053-2296
%D 2011
