Acta Crystallographica Section E: Structure Reports Online, ( ISI ), Volume (67), No (67), Year (2011-12) , Pages (1824-1825)
Title : ( [S-Allyl-4-(4-hydroxy-2-oxidobenzylideneideneisothiosemicarbazidato-N1,N4]-(ethanol-jO)dioxidouranium(VI) ethanolmonosolvate )
Authors: Reza Takjoo , Grzegorz Dutkiewicz , Maciej Kubicki ,File:
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Abstract
In the title compound, [U(C18H15N3O3S)O2(C2H5OH)]-C2H5OH, the UVI ion is in a distorted pentagonal–bipyramidal coordination geometry, with two oxide O atoms in axial sites. Two N and two O atoms of the tetradentate ligand and an O atom of an ethanol ligand form the equatorial plane. The dihedral angle between the mean planes of the two benzene rings is 34.8 (3). In the crystal, relatively strong O—H O hydrogen bonds connect the complex and ethanol solvent molecules into alternating centrosymmetric R2 2(8) and R4 4(16) ring motifs, forming chains along [100]. Weak intermolecular C—H O hydrogen bonds are also present.