Title : ( [S-Allyl-4-(4-hydroxy-2-oxidobenzylideneideneisothiosemicarbazidato-N1,N4]-(ethanol-jO)dioxidouranium(VI) ethanolmonosolvate )
Authors: Reza Takjoo , Grzegorz Dutkiewicz , Maciej Kubicki ,
Full TextAbstract
In the title compound, [U(C18H15N3O3S)O2(C2H5OH)]-C2H5OH, the UVI ion is in a distorted pentagonal–bipyramidal coordination geometry, with two oxide O atoms in axial sites. Two N and two O atoms of the tetradentate ligand and an O atom of an ethanol ligand form the equatorial plane. The dihedral angle between the mean planes of the two benzene rings is 34.8 (3). In the crystal, relatively strong O—H O hydrogen bonds connect the complex and ethanol solvent molecules into alternating centrosymmetric R2 2(8) and R4 4(16) ring motifs, forming chains along [100]. Weak intermolecular C—H O hydrogen bonds are also present.
Keywords
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@article{paperid:1024968,
author = {Takjoo, Reza and Grzegorz Dutkiewicz and Maciej Kubicki},
title = {[S-Allyl-4-(4-hydroxy-2-oxidobenzylideneideneisothiosemicarbazidato-N1,N4]-(ethanol-jO)dioxidouranium(VI) ethanolmonosolvate},
journal = {Acta Crystallographica Section E: Structure Reports Online},
year = {2011},
volume = {67},
number = {67},
month = {December},
issn = {1600-5368},
pages = {1824--1825},
numpages = {1},
keywords = {-},
}
%0 Journal Article
%T [S-Allyl-4-(4-hydroxy-2-oxidobenzylideneideneisothiosemicarbazidato-N1,N4]-(ethanol-jO)dioxidouranium(VI) ethanolmonosolvate
%A Takjoo, Reza
%A Grzegorz Dutkiewicz
%A Maciej Kubicki
%J Acta Crystallographica Section E: Structure Reports Online
%@ 1600-5368
%D 2011
