Title : ( Bis(l-pyridine-2,3-dicarboxylato)bis[aqua(3-carboxypyridine-2-carboxylato indium(III)] tetrahydrate) )
Authors: Hossein Eshtiagh Hosseini , Masoud Mirzaei Shahrabi , bibi azam moosavi nejad , M. Necas , J. T. Mague ,
Full TextAbstract
In the binuclear centrosymmetric title compound, [In2(C7H3NO4)2(C7H4NO4)2(H2O)2]4H2O, which contains both pyridine-2,3-dicarboxylate and 3-carboxypyridine-2- carboxylate ligands, the InIII atom is six-coordinated in a distorted octahedral geometry. One pyridine ligand is N,Ochelated while the other is N,O-chelated and at the same time bridging to the other via the second carboxyl group. In the crystal, an extensive O—H O hydrogen-bonding network, involving the coordinated and lattice water molecules and the carboxyl groups of the ligands, together with C—H O and – interactions [centroid–centroid distance = 3.793 (1) A ° ], leads to the formation of a three-dimensional structure.
Keywords
, single, crystal X, ray study; T = 120 K; mean (C–C) = 0.003 A° ; R factor = 0.016; wR factor = 0.039; data, to, parameter ratio = 13.3.
@article{paperid:1024978,
author = {Eshtiagh Hosseini, Hossein and Mirzaei Shahrabi, Masoud and Moosavi Nejad, Bibi Azam and M. Necas and J. T. Mague},
title = {Bis(l-pyridine-2,3-dicarboxylato)bis[aqua(3-carboxypyridine-2-carboxylato indium(III)] tetrahydrate)},
journal = {Acta Crystallographica Section E: Structure Reports Online},
year = {2011},
volume = {68},
number = {68},
month = {December},
issn = {1600-5368},
pages = {71--72},
numpages = {1},
keywords = {single-crystal X-ray study; T = 120 K; mean (C–C) = 0.003 A°
;
R factor = 0.016; wR factor = 0.039; data-to-parameter ratio = 13.3.},
}
%0 Journal Article
%T Bis(l-pyridine-2,3-dicarboxylato)bis[aqua(3-carboxypyridine-2-carboxylato indium(III)] tetrahydrate)
%A Eshtiagh Hosseini, Hossein
%A Mirzaei Shahrabi, Masoud
%A Moosavi Nejad, Bibi Azam
%A M. Necas
%A J. T. Mague
%J Acta Crystallographica Section E: Structure Reports Online
%@ 1600-5368
%D 2011
