Title : ( Bis[μ-4-(2-oxidobenzylidene)thiosemicarbazidato-κ4S,N1,O:O]bis[(pyridine-κN)zinc] )
Authors: Reza Takjoo , Grzegorz Dutkiewicz , Mehdi Ahmadi , Maciej Kubicki ,
Full TextAbstract
In the title compound, [Zn2(C8H7N3OS)2(C5H5N)2], the Zn2O2 ring has a flattened roof shape, with the roof angle equal to 10.10 (6). The hiosemicarbazones act as tridentate ligands to one ZnII atom, with the O atoms additionally in bridging positions to the second ZnII atom. Both ZnII atoms are five-coordinated; the coordination polyhedra are close to square pyramids, with the pyridine N atoms at apical positions. Two ntermolecular N—H...N and one relatively weak N—H S hydrogen bond, together with C—H...S weak interactions, connect the molecules into a three-dimensional network.
Keywords
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@article{paperid:1025329,
author = {Takjoo, Reza and Grzegorz Dutkiewicz and Mehdi Ahmadi and Maciej Kubicki},
title = {Bis[μ-4-(2-oxidobenzylidene)thiosemicarbazidato-κ4S,N1,O:O]bis[(pyridine-κN)zinc]},
journal = {Acta Crystallographica Section E: Structure Reports Online},
year = {2012},
volume = {62},
month = {January},
issn = {1600-5368},
pages = {106--107},
numpages = {1},
keywords = {-},
}
%0 Journal Article
%T Bis[μ-4-(2-oxidobenzylidene)thiosemicarbazidato-κ4S,N1,O:O]bis[(pyridine-κN)zinc]
%A Takjoo, Reza
%A Grzegorz Dutkiewicz
%A Mehdi Ahmadi
%A Maciej Kubicki
%J Acta Crystallographica Section E: Structure Reports Online
%@ 1600-5368
%D 2012
