Title : ( {4-Bromo-2-[(2-{(ethylsulfanyl)[(2-oxidobenzylidene-jO)amino-jN]methylidene}hydrazinylidene-jN1)methyl]-phenolato-jO}(butan-2-ol-jO)dioxidouranium(VI) )
Authors: Reza Takjoo , Mahdi Ahmadi , Seik Weng Ng , Edward R. T. Tiekink ,
Full TextAbstract
The UVI cation in the title complex, [U(C17H14BrN3O2S)O2-(C4H10O)], exists within a distorted pentagonal–bipyramidal geometry, where the oxide atoms occupy the axial positions [O—U—O = 179.8 (3)] and the pentagonal plane is defined by the N2O2 atoms of the tetradentate Schiff base ligand and the O atom of the 2-butanol molecule. In the crystal, centrosymmetric aggregates are formed via pairs of hydroxy–phenolate O—H...O hydrogen bonds. The azomethine C N atoms, the ethylthiolyl group, the 2-butanol molecule and Br atom are disordered over two positions in a 0.627 (3):0.373 (3) ratio.
Keywords
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@article{paperid:1025990,
author = {Takjoo, Reza and Mahdi Ahmadi and Seik Weng Ng and Edward R. T. Tiekink},
title = {{4-Bromo-2-[(2-{(ethylsulfanyl)[(2-oxidobenzylidene-jO)amino-jN]methylidene}hydrazinylidene-jN1)methyl]-phenolato-jO}(butan-2-ol-jO)dioxidouranium(VI)},
journal = {Acta Crystallographica Section E: Structure Reports Online},
year = {2012},
volume = {68},
month = {February},
issn = {1600-5368},
pages = {279--280},
numpages = {1},
keywords = {-},
}
%0 Journal Article
%T {4-Bromo-2-[(2-{(ethylsulfanyl)[(2-oxidobenzylidene-jO)amino-jN]methylidene}hydrazinylidene-jN1)methyl]-phenolato-jO}(butan-2-ol-jO)dioxidouranium(VI)
%A Takjoo, Reza
%A Mahdi Ahmadi
%A Seik Weng Ng
%A Edward R. T. Tiekink
%J Acta Crystallographica Section E: Structure Reports Online
%@ 1600-5368
%D 2012
