Title : ( (Dimethyl sulfoxide-jO)[2-({(ethylsulfanyl)[2-(2-oxidobenzylidene-jO)hydrazinylidene-N2]methyl}iminomethyl)-phenolato-jO]dioxidouranium(VI) )
Authors: Reza Takjoo , Seik Weng Ng , Edward R. T.Tiekink ,
Full TextAbstract
The UVI atom in the title complex, [U(C17H15N3O2S)O2-(C2H6OS)], exists within a distorted pentagonal–pyramidal geometry where the oxide atoms occupy axial positions [O—U—O = 177.84 (14)] and the pentagonal plane is defined by the N2O2 atoms of the tetradentate Schiff base ligand and the O atom of the dimethyl sulfoxide molecule. In the crystal, centrosymmetric aggregates are formed via pairs of C—H...O interactions. The azomethine C N atoms and ethylthiolyl group are disordered over two orientations in a 0.828 (3):0.172 (3) ratio.
Keywords
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@article{paperid:1025991,
author = {Takjoo, Reza and Seik Weng Ng and Edward R. T.Tiekink},
title = {(Dimethyl sulfoxide-jO)[2-({(ethylsulfanyl)[2-(2-oxidobenzylidene-jO)hydrazinylidene-N2]methyl}iminomethyl)-phenolato-jO]dioxidouranium(VI)},
journal = {Acta Crystallographica Section E: Structure Reports Online},
year = {2012},
volume = {68},
month = {February},
issn = {1600-5368},
pages = {244--245},
numpages = {1},
keywords = {-},
}
%0 Journal Article
%T (Dimethyl sulfoxide-jO)[2-({(ethylsulfanyl)[2-(2-oxidobenzylidene-jO)hydrazinylidene-N2]methyl}iminomethyl)-phenolato-jO]dioxidouranium(VI)
%A Takjoo, Reza
%A Seik Weng Ng
%A Edward R. T.Tiekink
%J Acta Crystallographica Section E: Structure Reports Online
%@ 1600-5368
%D 2012
