Title : ( (Butan-2-ol-jO)[2-({(ethylsulfanyl)-[2-(2-oxidobenzylidene-jO)hydrazinylidene-kN2]methyl}iminomethyl)-phenolato-jO]dioxidouranium(VI) )
Authors: Reza Takjoo , Atefeh Najafi , Seik Weng Ng , Edward R. T. Tiekink ,
Full TextAbstract
The U atom in the title complex, [U(C17H15N3O2S)O2-(C4H10O)], exists within a distorted pentagonal–bipyramidal geometry where the oxide O atoms occupy axial positions [O—U—O = 179.61 (18)] and the pentagonal plane is defined by the N2O2 atoms of the tetradentate Schiff base ligand and the O atom of the butan-2-ol molecule. In the crystal, centrosymmetric aggregates are formed via pairs of hydroxy–phenoxide O—H...O hydrogen bonds. The azomethine C N atoms, the ethylthiolyl group and the butyl group of the butan-2-ol molecule are disordered over two positions in a 0.668 (3):0.332 (3) ratio
Keywords
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@article{paperid:1025992,
author = {Takjoo, Reza and Najafi, Atefeh and Seik Weng Ng and Edward R. T. Tiekink},
title = {(Butan-2-ol-jO)[2-({(ethylsulfanyl)-[2-(2-oxidobenzylidene-jO)hydrazinylidene-kN2]methyl}iminomethyl)-phenolato-jO]dioxidouranium(VI)},
journal = {Acta Crystallographica Section E: Structure Reports Online},
year = {2012},
volume = {68},
month = {February},
issn = {1600-5368},
pages = {255--256},
numpages = {1},
keywords = {-},
}
%0 Journal Article
%T (Butan-2-ol-jO)[2-({(ethylsulfanyl)-[2-(2-oxidobenzylidene-jO)hydrazinylidene-kN2]methyl}iminomethyl)-phenolato-jO]dioxidouranium(VI)
%A Takjoo, Reza
%A Najafi, Atefeh
%A Seik Weng Ng
%A Edward R. T. Tiekink
%J Acta Crystallographica Section E: Structure Reports Online
%@ 1600-5368
%D 2012
