The late transition metal catalyst of [2,6-diacethylpyridinebis(2,6-diisopropylphenylimine)] cobalt(II) dichloride was prepared under controlled conditions and used for polymerization of ethylene. Methylaluminoxane (MAO) and triisobuthylaluminum (TIBA) were used as a cocatalyst and a scavenger, respectively. The highest activity of the catalyst was obtained at about 30_C; the activity decreased with increasing temperature. At polymerization temperatures higher than 50_C not only was a sharp decrease in the activity observed but also low molecular weight polyethylene product that was oily in appearance was obtained. The polymerization activity increased with increasing both of the monomer pressure and [MAO]:[Co] ratio. However, fouling of the reactor was strongly increased with increasing both of the monomer pressure and the amount of MAO used for the omogeneous polymerization. Hydrogen was used as the chain transfer. The activity of the catalyst and the viscosity average molecular weight (Mv) of the polymer obtained were not sensitive to hydrogen concentration. However, the viscosity average molecular weight of the polymer decreased with the monomer pressure. The (Mv), the melting point, and the crystallinity of the resulting polymer at the monomer pressure of 1 bar and polymerization temperature of 20_C were 1.2_105, 133_C, and 67%, respectively. Heterogeneous polymerization of ethylene using the catalyst and the MAO=SiO2 improved morphology of the resulting polymer; however, the activity of the catalyst was also decreased. Fouling of the reactor was eliminated using the supported catalyst system.

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