Title : ( Synergetic Effect of La and Ba Promoters on Nanostructured Iron Catalyst in Fischer-Tropsch Synthesis )
Authors: yahya zamani , Mehdi Bakavoli , Mohammad Rahimizadeh , Ali MOHAJERI , Seyed Mohammad Seyedi ,Abstract
Effect of promoters such as Barium and Lanthanum has been investigated on the conventional nanostructured iron catalyst in Fischer-Tropsch synthesis (FTS). The nanosized iron-based catalysts were prepared by a microemulsion method with the general formulation of 100Fe/4Cu, 100Fe/4Cu/2La, 100Fe/4Cu/ 1La/1Ba, and 100Fe/4Cu/2Ba. The phase, structure, and morphology of the catalysts were characterized by X-ray diffraction, N2 adsorption, transmission electron microscopy, temperature-programmed desorption of CO2, and temperature- programmed reduction. The results indicated that the addition of promoters could improve the activity of Fe catalysts for FTS and WGS (water-gas shift reaction) and lower the gas fraction at the outlet. In addition, both Ba- and La-promoted Fe catalysts exhibit the highest activity due to the synergetic effect.
Keywords
, nanosized iron catalyst; microemulsion method; Fischer, Tropsch synthesis; promoter effect@article{paperid:1028436,
author = {Zamani, Yahya and Bakavoli, Mehdi and Rahimizadeh, Mohammad and Ali MOHAJERI and Seyedi, Seyed Mohammad},
title = {Synergetic Effect of La and Ba Promoters on Nanostructured Iron Catalyst in Fischer-Tropsch Synthesis},
journal = {Chinese Journal of Catalysis},
year = {2012},
volume = {33},
number = {7},
month = {July},
issn = {0253-9837},
pages = {1119--1124},
numpages = {5},
keywords = {nanosized iron catalyst; microemulsion method; Fischer-Tropsch synthesis; promoter effect},
}
%0 Journal Article
%T Synergetic Effect of La and Ba Promoters on Nanostructured Iron Catalyst in Fischer-Tropsch Synthesis
%A Zamani, Yahya
%A Bakavoli, Mehdi
%A Rahimizadeh, Mohammad
%A Ali MOHAJERI
%A Seyedi, Seyed Mohammad
%J Chinese Journal of Catalysis
%@ 0253-9837
%D 2012