Tetrahedron, ( ISI ), Volume (68), No (38), Year (2012-8) , Pages (8046-8051)

Title : ( Diastereoselective synthesis of 5-iminooxazolines and their subsequent transformation to α,α-disubstituted dipeptide esters: a formal [4+1] cycloaddition reaction of cyclohexyl isocyanide and Z-alkyl-α-benzoyl amino-acrylates )

Authors: Abbas Ali Esmaeili , Shima Shahmansouri , Azizollah Habibi , Ali Reza Fakhari ,

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A novel atom economical diastereoselective synthesis of 5-iminooxazolines and their subsequent transformation to α,α-disubstituted dipeptide esters is described. Heating a mixture of cyclohexyl isocyanide and Z-α-benzoyl amino-acrylic acid alkyl esters under solvent-free conditions, afforded 5-iminooxazolines, which, upon specifications provided α,α-disubstituted dipeptide esters in good yield.

Keywords

, 5, Iminooxazolines a, Amidoacrylates Cyclohexyl isocyanide [4þ1] Cycloaddition Solvent, free
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@article{paperid:1029124,
author = {Esmaeili, Abbas Ali and Shima Shahmansouri and Azizollah Habibi and Ali Reza Fakhari},
title = {Diastereoselective synthesis of 5-iminooxazolines and their subsequent transformation to α,α-disubstituted dipeptide esters: a formal [4+1] cycloaddition reaction of cyclohexyl isocyanide and Z-alkyl-α-benzoyl amino-acrylates},
journal = {Tetrahedron},
year = {2012},
volume = {68},
number = {38},
month = {August},
issn = {0040-4020},
pages = {8046--8051},
numpages = {5},
keywords = {5-Iminooxazolines a-Amidoacrylates Cyclohexyl isocyanide [4þ1] Cycloaddition Solvent-free synthesis},
}

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%0 Journal Article
%T Diastereoselective synthesis of 5-iminooxazolines and their subsequent transformation to α,α-disubstituted dipeptide esters: a formal [4+1] cycloaddition reaction of cyclohexyl isocyanide and Z-alkyl-α-benzoyl amino-acrylates
%A Esmaeili, Abbas Ali
%A Shima Shahmansouri
%A Azizollah Habibi
%A Ali Reza Fakhari
%J Tetrahedron
%@ 0040-4020
%D 2012

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