Title : ( [2-(1-{2-[Azanidyl(ethylsulfanyl)methylidene-jN]hydrazin-1-ylidene-jN1}ethyl)-phenolato-jO](pyridine-jN)nickel(II) )
Authors: Reza Takjoo , Seik Weng Ng , Edward R. T.Tiekink ,
Full TextAbstract
The NiII atom in the title complex, [Ni(C11H13N3OS)- (C5H5N)], exists within a square-planar N3O donor set provided by N,N0,O atoms of the dianionic tridentate ligand and a pyridine N atom. The maximum deviation from the ideal geometry is seen in the N—Ni—N five-membered chelate bite angle of 83.28 (12)_. The pyridine molecule forms a dihedral angle of 44.43 (6)_ with the N3O donor set. Supramolecular stacks along the a axis mediated by alternating _–_ interactions between the pyridine and five- [centroid–centroid distance = 3.4784 (16) A ° ] and six-membered [3.4633 (17) A ° ] chelate rings, feature in the crystal packing.
Keywords
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@article{paperid:1029156,
author = {Takjoo, Reza and Seik Weng Ng and Edward R. T.Tiekink},
title = {[2-(1-{2-[Azanidyl(ethylsulfanyl)methylidene-jN]hydrazin-1-ylidene-jN1}ethyl)-phenolato-jO](pyridine-jN)nickel(II)},
journal = {Acta Crystallographica Section E: Structure Reports Online},
year = {2012},
volume = {68},
month = {July},
issn = {1600-5368},
pages = {911--911},
numpages = {0},
keywords = {-},
}
%0 Journal Article
%T [2-(1-{2-[Azanidyl(ethylsulfanyl)methylidene-jN]hydrazin-1-ylidene-jN1}ethyl)-phenolato-jO](pyridine-jN)nickel(II)
%A Takjoo, Reza
%A Seik Weng Ng
%A Edward R. T.Tiekink
%J Acta Crystallographica Section E: Structure Reports Online
%@ 1600-5368
%D 2012
