Title : ( Characterization and Crystal Structure of Trans-Dichloro(Bis-Thiocarbohydrazide) Cadmium(II) )
Authors: M. Hakimi , N. Feizi , F. Abbasi , Reza Takjoo , E. Schuh , F. Mohr ,
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Abstract
The preparation and spectroscopic characterization of trans-dichloro(bisthiocarbohydrazide) cadmium(II) using UV–Vis, Raman and IR spectroscopies is reported is reported in this paper. Molecular structure of the complex was determined by single-crystal X-ray diffraction. The compound crystallizes in the monoclinic crystal system, space group P21/n, Z = 4, V = 594.91(5) Å3 with unit cell parameters a = 8.6136(4) Å, b = 5.7881(3) Å, c = 12.0980(6) Å and β = 99.487(5) º. The cadmium (II) ion is bound to sulfur and nitrogen atoms of two thiocarbohydrazide ligands as well as two chloride ions in an octahedral geometry about Cd.
Keywords
Thiocarbohydrazide; Cadmium (II); Hydrogen bonding; Crystal structure.
@article{paperid:1029245,
author = {M. Hakimi and N. Feizi and F. Abbasi and Takjoo, Reza and E. Schuh and F. Mohr},
title = {Characterization and Crystal Structure of Trans-Dichloro(Bis-Thiocarbohydrazide) Cadmium(II)},
journal = {Journal of the Chemical Society of Pakistan},
year = {2012},
volume = {34},
number = {3},
month = {May},
issn = {0253-5106},
pages = {679--682},
numpages = {3},
keywords = {Thiocarbohydrazide; Cadmium (II); Hydrogen bonding; Crystal structure.},
}
%0 Journal Article
%T Characterization and Crystal Structure of Trans-Dichloro(Bis-Thiocarbohydrazide) Cadmium(II)
%A M. Hakimi
%A N. Feizi
%A F. Abbasi
%A Takjoo, Reza
%A E. Schuh
%A F. Mohr
%J Journal of the Chemical Society of Pakistan
%@ 0253-5106
%D 2012
