Title : ( Complexes with cis-MoO2 unit of new isothiosemicarbazone )
Authors: Reza Takjoo , M. Ahmadi , A. Akbari , H. Amiri Rudbari , F. Nicolo ,
Full TextAbstract
A new 5-bromo-2-hydroxobenzaldehyde S-ethylisothiosemicarbazone hydroiodide free Schiff base (H2L) is synthesized and a series of molybdenum(VI) complexes, MoIVO2LD, have prepared where D can be DMF, DMSO and pyridine. The compounds are characterized with molar conductance, FT-IR, 1H NMR, elemental analyses, and UV-Vis techniques. Structures of complexes are determined with X-ray analysis. All experimental results confirmed that H2L is a tridentate bi-deprotonated ligand (ONN), coordinating through phenolic oxygen, azomethine nitrogen, and isothioamide nitrogen. The neutral complexes are distorted octahedral.
Keywords
, Isothiosemicarbazone; Molybdenum(VI) complex; cis, MoO2; Spectral study; Crystal structure
@article{paperid:1029248,
author = {Takjoo, Reza and M. Ahmadi and A. Akbari and H. Amiri Rudbari and F. Nicolo},
title = {Complexes with cis-MoO2 unit of new isothiosemicarbazone},
journal = {Journal of Coordination Chemistry},
year = {2012},
volume = {65},
number = {19},
month = {August},
issn = {0095-8972},
pages = {3403--3412},
numpages = {9},
keywords = {Isothiosemicarbazone; Molybdenum(VI) complex; cis-MoO2; Spectral study; Crystal structure},
}
%0 Journal Article
%T Complexes with cis-MoO2 unit of new isothiosemicarbazone
%A Takjoo, Reza
%A M. Ahmadi
%A A. Akbari
%A H. Amiri Rudbari
%A F. Nicolo
%J Journal of Coordination Chemistry
%@ 0095-8972
%D 2012
