Title : ( Synthesis and characterization of some new Schiff base complexes of group 13 elements, ab initio studies, cytotoxicity and reaction with hydrogen peroxide )
Authors: M. Asadi , Z. Asadi , N. Savaripoor , M. H. Ghatee , Fatemeh Moosavi , R. Yousefi , M. Jamshidi ,
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Abstract
A novel tetradentate Schiff base, naphthabza-H2 = N,N’-bis(naphthylidene)-2-aminobenzylamine, and a series of aluminum(III), gallium(III), and indium(III) complexes with general formula, MLNO3, were synthesized and characterized by elemental analysis, 1H NMR, FT-IR, UV-Vis spectroscopy and thermogravimetric method. The product of the reaction of complexes with hydrogen peroxide was characterized by similar techniques. According to the ab initio calculations aluminum and gallium complexes have five-coordinated structures and indium complex is a six-coordinated one. Also, the growth inhibitory effects of the complexes toward K562 cancer cell line were measured and the results for these complexes are as follows: Al> Ga> In
Keywords
Aluminum Gallium Indium Schiff base Ab initio studies Hydrogen Peroxide
@article{paperid:1029888,
author = {M. Asadi and Z. Asadi and N. Savaripoor and M. H. Ghatee and Moosavi, Fatemeh and R. Yousefi and M. Jamshidi},
title = {Synthesis and characterization of some new Schiff base complexes of group 13 elements, ab initio studies, cytotoxicity and reaction with hydrogen peroxide},
journal = {Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy},
year = {2012},
volume = {101},
month = {September},
issn = {1386-1425},
pages = {394--399},
numpages = {5},
keywords = {Aluminum
Gallium
Indium
Schiff base
Ab initio studies
Hydrogen Peroxide},
}
%0 Journal Article
%T Synthesis and characterization of some new Schiff base complexes of group 13 elements, ab initio studies, cytotoxicity and reaction with hydrogen peroxide
%A M. Asadi
%A Z. Asadi
%A N. Savaripoor
%A M. H. Ghatee
%A Moosavi, Fatemeh
%A R. Yousefi
%A M. Jamshidi
%J Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
%@ 1386-1425
%D 2012
