Title : ( N,N-Dimethyl-N-,N-- -bis(2-methyl-phenyl)phosphoric triamide monohydrate )
Authors: Farnaz Eslami , Mehrdad Pourayoubi , Mohammad Yousefi , Arnold L. Rheingold , James A. Golen ,
Full TextAbstract
In the title compound, C16H22N3OP.H2O, the P atom adopts a distorted tetrahedral environment with the bond angles around the P atom in the range 99.98 (7)–116.20 (7)°. The P—N bond length in the [(CH3)2N]P(O) fragment [1.6392 (14) Å] is slightly shorter than two other P—N bonds [1.6439 (15) and 1.6530 (14) Å]. In the (CH3)2NP(O) fragment, one of the methyl groups is syn to the P═O bond, whereas the other one is anti to the P═O bond [C—N—P O torsion angles = 4.80 (17) and –174.57 (15)°]. In the crystal, the water molecules form hydrogen bonds to the O atoms of the P═O bond of two different molecules and act as acceptors for the two amino H atoms of the same molecule. As a result, chains parallel to [010] are formed.
Keywords
, single, crystal X, ray study; T = 100 K; mean σ(C–C) = 0.003 Å; R factor = 0.043; wR factor = 0.115; data, to, parameter ratio = 18.8.
@article{paperid:1030499,
author = {Farnaz Eslami and Pourayoubi, Mehrdad and Mohammad Yousefi and Arnold L. Rheingold and James A. Golen},
title = {N,N-Dimethyl-N-,N-- -bis(2-methyl-phenyl)phosphoric triamide monohydrate},
journal = {Acta Crystallographica Section E: Structure Reports Online},
year = {2012},
volume = {68},
number = {9},
month = {September},
issn = {1600-5368},
pages = {2650--2650},
numpages = {0},
keywords = {single-crystal X-ray study; T = 100 K; mean σ(C–C) = 0.003 Å; R factor = 0.043; wR factor = 0.115; data-to-parameter ratio = 18.8.},
}
%0 Journal Article
%T N,N-Dimethyl-N-,N-- -bis(2-methyl-phenyl)phosphoric triamide monohydrate
%A Farnaz Eslami
%A Pourayoubi, Mehrdad
%A Mohammad Yousefi
%A Arnold L. Rheingold
%A James A. Golen
%J Acta Crystallographica Section E: Structure Reports Online
%@ 1600-5368
%D 2012
